Steam explosion treatment of Eucalyptus globulus wood Influence of operational conditions on chemical and structural modifications

This study evaluates the use of steam explosion (SE) as a pre-treatment of Eucalyptus globulus chips, aimed at making this wood suitable as feedstock in biorefineries or alternative processes such as biopulping. Several SE treatments were applied, modifying the following variables previous hydration...

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Detalles Bibliográficos
Autores: Martín-Sampedro, Raquel, Martín, Juan Antonio, Eugenio, María E., Revilla, Eloy, Villar, J. C.
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2011
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/289964
Acceso en línea:http://hdl.handle.net/10261/289964
Access Level:acceso abierto
Palabra clave:Eucalyptus globulus
Biorefinery
Steam explosion
Porosity
Descripción
Sumario:This study evaluates the use of steam explosion (SE) as a pre-treatment of Eucalyptus globulus chips, aimed at making this wood suitable as feedstock in biorefineries or alternative processes such as biopulping. Several SE treatments were applied, modifying the following variables previous hydration of the chips, number of SE cycles, and duration of the first cycle. Chemical composition and structural properties were analyzed after all treatments. Our results show that acetone and hot water extractives contents increased between 1.0% and 6.2% and between 3.6% and 7.1%, respectively, depending on SE operational conditions. Holocellulose content was also observed to decrease (9.4 to 15.6%), while the Klason lignin underwent a slight solubilization. Furthermore, greater water retention capacity and new bigger sized pores were found in the exploded samples. It is reasonable to expect that these changes would facilitate the subsequent implementation of chemical or biological treatments of the cellulose fraction in the biorefinery design.