Use of a voltammetric electronic tongue for predicting levels of nerve agent mimics

[EN] An electronic tongue (ET) based on pulse voltammetry containing a set of eight metallic electrodes (Au, Pt, Ir, Rh, Cu, Co, Ni and Ag) encapsulated on a stainless steel cylinder has been used to discriminate and predict levels of nerve agent mimics in aqueous environments. Analysis including pr...

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Detalles Bibliográficos
Autores: Campos Sánchez, Inmaculada, Soto Camino, Juan, Gil Sánchez, Luís|||0000-0003-3453-5559, Martínez-Máñez, Ramón|||0000-0001-5873-9674, Vivancos, José-Luis|||0000-0002-8524-5466
Tipo de recurso: artículo
Fecha de publicación:2009
País:España
Institución:Universitat Politècnica de València (UPV)
Repositorio:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
Idioma:inglés
OAI Identifier:oai:riunet.upv.es:10251/100407
Acceso en línea:https://riunet.upv.es/handle/10251/100407
Access Level:acceso abierto
Palabra clave:Electronic tongue
Voltammetry
Nerve agent mimics
PROYECTOS DE INGENIERIA
QUIMICA INORGANICA
TECNOLOGIA ELECTRONICA
QUIMICA ANALITICA
Descripción
Sumario:[EN] An electronic tongue (ET) based on pulse voltammetry containing a set of eight metallic electrodes (Au, Pt, Ir, Rh, Cu, Co, Ni and Ag) encapsulated on a stainless steel cylinder has been used to discriminate and predict levels of nerve agent mimics in aqueous environments. Analysis including principal component analysis (PCA) and partial least square techniques (PLS) have been applied for data management and prediction models. A good discrimination from other organophosphorous derivatives was found for the nerve agent simulants diethyl-chlorophosphate (DCP) and diethyl-cyanophosphate (DCNP).