Bacterial cellulose/graphene oxide aerogels with enhanced dimensional and thermal stability

We present a novel method for processing bacterial cellulose/graphene oxide (BC/GO) aerogels with multifunctional properties. The addition of a small amount of dimethyl sulfoxide (DMSO) to the aqueous dispersion of the nanomaterials during the gelification process affected the water freezing tempera...

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Detalhes bibliográficos
Autores: Pinto, Susana C., Gonçalves, Gil, Sandoval, Stefania, López Periago, Ana M., Borrás, Alejandro, Domingo, Concepción, Tobias, Gerard, Duarte, Isabel, Vicente, Romeu, Marques, Paula A.A.P.
Formato: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2020
País:España
Recursos:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/220929
Acesso em linha:http://hdl.handle.net/10261/220929
Access Level:acceso abierto
Palavra-chave:Bacterial cellulose
Graphene oxide
Reduction treatments
Dimensional stability
Thermal stability
Descrição
Resumo:We present a novel method for processing bacterial cellulose/graphene oxide (BC/GO) aerogels with multifunctional properties. The addition of a small amount of dimethyl sulfoxide (DMSO) to the aqueous dispersion of the nanomaterials during the gelification process affected the water freezing temperature of the system and thereby affecting the porous structure of the aerogel obtained after liophilization. The possibility to obtain small and elongated pore with axial orientation allowed a significant improvement of the structural stability of the aerogels. Moreover, the aerogels reduction by thermal treatment with ammonia gas induced crosslinking between the different nanophases, thus given an incremental factor for the mechanical performance of the aerogels under harsh conditions. The resulting aerogels also showed significant improvements in terms of thermal stability and electrical conductivity. These multifunctional BC/GO aerogels present high potential as sustainable and ecological alternative materials for lightweight packaging, filters for atmosphere and water treatment, or energy applications.