Toward a new PTCR material based on the Na2Ti6O13/Na2Ti3O7 system

Mixed phases of sodium titanate ceramics are obtained using both conventional and laser sintering methods. It was observed a clear dependence on the structural, microstructural and electrical resistivity with the employed sintering method. The temperature dependence of the resistivity in the ceramic...

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Detalles Bibliográficos
Autores: Basilio, L.A.L., Silva, J.H.L., Xavier, F., Aguilera, Lianet, Guerrero, Fidel, Antonelli, Eduardo, Anglada-Rivera, José, García García, José Eduardo|||0000-0002-1232-1739, Silva, R.S., Leyet, Yurimiler
Tipo de recurso: artículo
Fecha de publicación:2021
País:España
Institución:Universitat Politècnica de Catalunya (UPC)
Repositorio:UPCommons. Portal del coneixement obert de la UPC
Idioma:inglés
OAI Identifier:oai:upcommons.upc.edu:2117/342593
Acceso en línea:https://hdl.handle.net/2117/342593
https://dx.doi.org/10.1016/j.materresbull.2021.111311
Access Level:acceso abierto
Palabra clave:Sintering
Sodium titanate
Laser sintering
Resistivity
PTCR
Sinterització
Àrees temàtiques de la UPC::Física
Descripción
Sumario:Mixed phases of sodium titanate ceramics are obtained using both conventional and laser sintering methods. It was observed a clear dependence on the structural, microstructural and electrical resistivity with the employed sintering method. The temperature dependence of the resistivity in the ceramics shows an increase of three orders of magnitude in a narrow range of temperatures, thereby indicating a noticeable positive temperature coefficient of resistivity (PTCR) effect. To explain this observed abnormal behavior, a model based on the structure of the Na2Ti6O13/Na2Ti3O7 composite is proposed. A new class of PTCR materials is reported.