Effect of ternary cements containing thermally activated paper sludge and fly ash on the texture of C–S–H gel

The texture of the C–S–H gels formed in ternary cement blends containing thermally activated paper sludge (APS), fly ash (FA) from coal combustion and Ordinary Portland Cement (OPC) was studied by means of the specific surface area (SSA) and pore-size distribution (PSD), which were measured by the s...

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Bibliographic Details
Authors: Goñi Elizalde, Sara, Frías, Moisés, Vegas, Iñigo, García, R., Vigil de la Villa, R.
Format: article
Publication Date:2012
Country:España
Institution:Consejo Superior de Investigaciones Científicas (CSIC)
Repository:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/57782
Online Access:http://hdl.handle.net/10261/57782
Access Level:Embargoed access
Keyword:Blended cement
Hydration
Calcium silicate hydrate
Surface area
Compressive strength
Description
Summary:The texture of the C–S–H gels formed in ternary cement blends containing thermally activated paper sludge (APS), fly ash (FA) from coal combustion and Ordinary Portland Cement (OPC) was studied by means of the specific surface area (SSA) and pore-size distribution (PSD), which were measured by the sorption isotherms of nitrogen gas and the BET method. Two differentiated zones in the PSD of the C–S–H gel at ∼10–20 nm and ∼5 nm were observed. The proportion of such zones depends on the age of hydration and amount of OPC replacement. The incorporation of the additions (APS and FA) clearly revealed an increase in both porosity and SSA. This effect decreased with the progress of hydration together with a refinement of the nano-porous structure of C–S–H. High correlations were found among these nanostructure characteristics of the C–S–H gel and mechanical strengths.