GC-EoS extension to alkylphosphate imidazolium ionic liquids

Producción Científica

Detalles Bibliográficos
Autores: Pablo Nisa, Laura de, Sánchez, Francisco A., Bermejo Roda, Maria Dolores, Pereda, Selva
Tipo de recurso: artículo
Estado:Versión borrador
Fecha de publicación:2019
País:España
Institución:Universidad de Valladolid
Repositorio:UVaDOC. Repositorio Documental de la Universidad de Valladolid
OAI Identifier:oai:uvadoc.uva.es:10324/37283
Acceso en línea:https://doi.org/10.1016/j.fluid.2018.09.022
http://uvadoc.uva.es/handle/10324/37283
Access Level:acceso abierto
Palabra clave:Ionic liquidsGroup contributionEquation of state1-alkyl-3-methylimidazolium dimethylphosphate1-alkyl-3-methylimidazolium diethylphosphateGC-EoS
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spelling GC-EoS extension to alkylphosphate imidazolium ionic liquidsPablo Nisa, Laura deSánchez, Francisco A.Bermejo Roda, Maria DoloresPereda, SelvaIonic liquidsGroup contributionEquation of state1-alkyl-3-methylimidazolium dimethylphosphate1-alkyl-3-methylimidazolium diethylphosphateGC-EoSProducción CientíficaIn this work, the Group Contribution Equation of State (GC-EoS) is extended to model two new ionic liquid families, namely, 1-alkyl-3-methylimidazolium dimethylphosphate ([-MeIm]+[Me2PO4]-) and 1-alkyl-3-methylimidazolium diethylphosphate ([-MeIm]+[Et2PO4]-). Pure group parameters for the functional groups [-MeIm]+[Me2PO4]- and [-MeIm]+[Et2PO4]- and interaction parameters between these groups and the main paraffinic and aromatic subgroups (CH3, CH2, ACH, AC, ACCH3, CH2=CH) were estimated using infinite dilution activity coefficients from literature. In order to evaluate the performance of the new parameters, the model was compared with experimental data on the phase behavior of binary mixtures, showing an average relative deviation of 4.5%.MINECO proyecto ENE2014-53459-RMINECO Prorama Ramón y Cajal RYC-2013-13976Consejo Nacional de Investigaciones Científicas y Técnicas (PIP 112 2015 010 856)Ministerio de Ciencia, Tecnología e Innovación Productiva (PICT 2016 0907)Universidad Nacional del Sur (PGI - 24/M133)LP thanks the Erasmus Mundus EuricaElsevier2019info:eu-repo/semantics/articleinfo:eu-repo/semantics/draftapplication/pdfhttps://doi.org/10.1016/j.fluid.2018.09.022http://uvadoc.uva.es/handle/10324/37283reponame:UVaDOC. Repositorio Documental de la Universidad de Valladolidinstname:Universidad de ValladolidIngléshttps://doi.org/10.1016/j.fluid.2018.09.022info:eu-repo/semantics/openAccessoai:uvadoc.uva.es:10324/372832026-06-13T12:44:47Z
dc.title.none.fl_str_mv GC-EoS extension to alkylphosphate imidazolium ionic liquids
title GC-EoS extension to alkylphosphate imidazolium ionic liquids
spellingShingle GC-EoS extension to alkylphosphate imidazolium ionic liquids
Pablo Nisa, Laura de
Ionic liquidsGroup contributionEquation of state1-alkyl-3-methylimidazolium dimethylphosphate1-alkyl-3-methylimidazolium diethylphosphateGC-EoS
title_short GC-EoS extension to alkylphosphate imidazolium ionic liquids
title_full GC-EoS extension to alkylphosphate imidazolium ionic liquids
title_fullStr GC-EoS extension to alkylphosphate imidazolium ionic liquids
title_full_unstemmed GC-EoS extension to alkylphosphate imidazolium ionic liquids
title_sort GC-EoS extension to alkylphosphate imidazolium ionic liquids
dc.creator.none.fl_str_mv Pablo Nisa, Laura de
Sánchez, Francisco A.
Bermejo Roda, Maria Dolores
Pereda, Selva
author Pablo Nisa, Laura de
author_facet Pablo Nisa, Laura de
Sánchez, Francisco A.
Bermejo Roda, Maria Dolores
Pereda, Selva
author_role author
author2 Sánchez, Francisco A.
Bermejo Roda, Maria Dolores
Pereda, Selva
author2_role author
author
author
dc.subject.none.fl_str_mv Ionic liquidsGroup contributionEquation of state1-alkyl-3-methylimidazolium dimethylphosphate1-alkyl-3-methylimidazolium diethylphosphateGC-EoS
topic Ionic liquidsGroup contributionEquation of state1-alkyl-3-methylimidazolium dimethylphosphate1-alkyl-3-methylimidazolium diethylphosphateGC-EoS
description Producción Científica
publishDate 2019
dc.date.none.fl_str_mv 2019
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/draft
format article
status_str draft
dc.identifier.none.fl_str_mv https://doi.org/10.1016/j.fluid.2018.09.022
http://uvadoc.uva.es/handle/10324/37283
url https://doi.org/10.1016/j.fluid.2018.09.022
http://uvadoc.uva.es/handle/10324/37283
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv https://doi.org/10.1016/j.fluid.2018.09.022
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:UVaDOC. Repositorio Documental de la Universidad de Valladolid
instname:Universidad de Valladolid
instname_str Universidad de Valladolid
reponame_str UVaDOC. Repositorio Documental de la Universidad de Valladolid
collection UVaDOC. Repositorio Documental de la Universidad de Valladolid
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,301603

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