Bioleaching of Metal-Polluted Mine Tailings: A Comparative Approach Between Ex Situ Slurry-Phase Stirred Reactors Versus In Situ Electrokinetic Percolation

This work compares two technologies for the remediation of metal-polluted mine tailings based on lab-scale bioleaching experiments performed in (a) conventional agitated slurry-phase reactors and (b) in situ electrokinetic percolation. While ex situ bioleaching in agitated reactors has been widely s...

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Detalles Bibliográficos
Autores: Acosta Hernández, Irene, Muñoz Morales, Martín, Fernández Morales, Francisco Jesús, Rodríguez Romero, Luis, Villaseñor Camacho, José
Tipo de recurso: artículo
Fecha de publicación:2024
País:España
Institución:Universidad de Castilla-La Mancha
Repositorio:RUIdeRA. Repositorio Institucional de la UCLM
OAI Identifier:oai:ruidera.uclm.es:10578/42039
Acceso en línea:https://doi.org/10.3390/app142411756
https://hdl.handle.net/10578/42039
Access Level:acceso abierto
Palabra clave:bioleaching
electrokinetic percolation
metal pollution
mine tailing
slurry agitated reactor
soil remediation
Descripción
Sumario:This work compares two technologies for the remediation of metal-polluted mine tailings based on lab-scale bioleaching experiments performed in (a) conventional agitated slurry-phase reactors and (b) in situ electrokinetic percolation. While ex situ bioleaching in agitated reactors has been widely studied, only a few previous works have studied the in situ option that couples bioleaching and electrokinetics. Real mine tailings from an abandoned sphalerite mine in southern Spain were used. The leaching medium was externally generated in a bioreactor using an autochthonous acidophilic culture and then added to tailings in batch experiments. This medium enabled metal leaching from mine tailings without the stringent operating conditions required by a classic bioleaching process. Metal removal efficiencies and kinetic rate constants after 15 d of treatments were calculated. Additionally, advantages or disadvantages between the two methods were discussed. The results for the innovative EK-percolation method showed rates and efficiencies that were comparable to, and in some cases better than, those achieved with conventional stirred slurry systems.