Multitopic Corannulene-Porphyrin Hosts for Fullerenes: A Three-Layer Scaffold for Precisely Designed Supramolecular Ensembles

A method to synthesize coplanar dimeric porphyrins bearing eight corannulene units has been developed. It relies on the stability of octahedral CO-capped Ru(II) complexes linked by N-donor ligands. This specific arrangement provides an optimal scaffold to accommodate fullerenes by imposing corannule...

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Autores: Álvarez-Llorente, Nerea, Stasyuk, Anton J., Diez-Varga, Alberto, Solà i Puig, Miquel, Barbero, Héctor, Álvarez, Celedonio M.
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2025
País:España
Institución:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Repositorio:Recercat. Dipósit de la Recerca de Catalunya
OAI Identifier:oai:recercat.cat:10256/26007
Acceso en línea:http://hdl.handle.net/10256/26007
Access Level:acceso abierto
Palabra clave:Ful·lerens
Química supramolecular
Fullerenes
Supramolecular chemistry
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spelling Multitopic Corannulene-Porphyrin Hosts for Fullerenes: A Three-Layer Scaffold for Precisely Designed Supramolecular EnsemblesÁlvarez-Llorente, NereaStasyuk, Anton J.Diez-Varga, AlbertoSolà i Puig, MiquelBarbero, HéctorÁlvarez, Celedonio M.Ful·lerensQuímica supramolecularFullerenesSupramolecular chemistryA method to synthesize coplanar dimeric porphyrins bearing eight corannulene units has been developed. It relies on the stability of octahedral CO-capped Ru(II) complexes linked by N-donor ligands. This specific arrangement provides an optimal scaffold to accommodate fullerenes by imposing corannulene groups at precise distance and relative orientation. Their capabilities for C60 recognition have been thoroughly assessed, revealing that each system can encapsulate up to four buckyballs, giving rise to a compact supramolecular complex echoing a discrete donor-acceptor-donor trilayer offer-ing significant potential properties for further exploitationThe authors thank the SpanishMinistry of Science and Innovation (MCIN) (PID2021-124691NB-I00, funded by MCIN/AEI/10.13039/501100011033/FEDER,UE) for funding. N.A.-L. acknowledges the University of Valladolid and Santander Bank for apredoctoral contract.A.D.-V. acknowledges the Ministerio de Universidades and the European Union-Next Generation EU for the María Zambrano contract (ADV ,CONVREC-2021-264). M.S. is grateful for financial support from the Spanish Ministry of Science and Innovation (MCIN/AEI/10.13039/501100011033; Network RED202214939-T, Project PID2023-147424NB-I00) and the Catalan Conselleria de Recerca i Universitats of the Generalitat de Catalunya (Project 2021SGR623). A.J.S. is grateful for financial support from the Spanish Ministry of Science and Innovation (AEI/10.13039/501100011033, Grant CEX 2021001202-M) and also gratefully acknowledges Poland’s highperformance computing infrastructure PLGrid (HPC Centers: ACK Cyfronet AGH) for providing computer facilities and support within Computational Grants PLG/2023/016841American Chemical Society (ACS)Agencia Estatal de Investigación2025info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersion6 p.application/pdfhttp://hdl.handle.net/10256/26007http://hdl.handle.net/10256/26007Organic Letters, 2025, vol. 27, núm. 1, p. 357-362Articles publicats (D-Q)Álvarez-Llorente, Nerea Stasyuk, Anton J. Diez-Varga, Alberto Solà i Puig, Miquel Barbero, Héctor Álvarez, Celedonio M. 2025 Multitopic Corannulene-Porphyrin Hosts for Fullerenes: A Three-Layer Scaffold for Precisely Designed Supramolecular Ensembles Organic Letters 27 1 357 362reponame:Recercat. Dipósit de la Recerca de Catalunyainstname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)Inglésinfo:eu-repo/semantics/altIdentifier/doi/10.1021/acs.orglett.4c04385info:eu-repo/semantics/altIdentifier/issn/1523-7060info:eu-repo/semantics/altIdentifier/eissn/1523-7052PID2023-147424NB-I00info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023/PID2023-147424NB-I00Reconeixement 4.0 Internacionalhttp://creativecommons.org/licenses/by/4.0info:eu-repo/semantics/openAccessoai:recercat.cat:10256/260072026-05-29T05:05:01Z
dc.title.none.fl_str_mv Multitopic Corannulene-Porphyrin Hosts for Fullerenes: A Three-Layer Scaffold for Precisely Designed Supramolecular Ensembles
title Multitopic Corannulene-Porphyrin Hosts for Fullerenes: A Three-Layer Scaffold for Precisely Designed Supramolecular Ensembles
spellingShingle Multitopic Corannulene-Porphyrin Hosts for Fullerenes: A Three-Layer Scaffold for Precisely Designed Supramolecular Ensembles
Álvarez-Llorente, Nerea
Ful·lerens
Química supramolecular
Fullerenes
Supramolecular chemistry
title_short Multitopic Corannulene-Porphyrin Hosts for Fullerenes: A Three-Layer Scaffold for Precisely Designed Supramolecular Ensembles
title_full Multitopic Corannulene-Porphyrin Hosts for Fullerenes: A Three-Layer Scaffold for Precisely Designed Supramolecular Ensembles
title_fullStr Multitopic Corannulene-Porphyrin Hosts for Fullerenes: A Three-Layer Scaffold for Precisely Designed Supramolecular Ensembles
title_full_unstemmed Multitopic Corannulene-Porphyrin Hosts for Fullerenes: A Three-Layer Scaffold for Precisely Designed Supramolecular Ensembles
title_sort Multitopic Corannulene-Porphyrin Hosts for Fullerenes: A Three-Layer Scaffold for Precisely Designed Supramolecular Ensembles
dc.creator.none.fl_str_mv Álvarez-Llorente, Nerea
Stasyuk, Anton J.
Diez-Varga, Alberto
Solà i Puig, Miquel
Barbero, Héctor
Álvarez, Celedonio M.
author Álvarez-Llorente, Nerea
author_facet Álvarez-Llorente, Nerea
Stasyuk, Anton J.
Diez-Varga, Alberto
Solà i Puig, Miquel
Barbero, Héctor
Álvarez, Celedonio M.
author_role author
author2 Stasyuk, Anton J.
Diez-Varga, Alberto
Solà i Puig, Miquel
Barbero, Héctor
Álvarez, Celedonio M.
author2_role author
author
author
author
author
dc.contributor.none.fl_str_mv Agencia Estatal de Investigación
dc.subject.none.fl_str_mv Ful·lerens
Química supramolecular
Fullerenes
Supramolecular chemistry
topic Ful·lerens
Química supramolecular
Fullerenes
Supramolecular chemistry
description A method to synthesize coplanar dimeric porphyrins bearing eight corannulene units has been developed. It relies on the stability of octahedral CO-capped Ru(II) complexes linked by N-donor ligands. This specific arrangement provides an optimal scaffold to accommodate fullerenes by imposing corannulene groups at precise distance and relative orientation. Their capabilities for C60 recognition have been thoroughly assessed, revealing that each system can encapsulate up to four buckyballs, giving rise to a compact supramolecular complex echoing a discrete donor-acceptor-donor trilayer offer-ing significant potential properties for further exploitation
publishDate 2025
dc.date.none.fl_str_mv 2025
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10256/26007
http://hdl.handle.net/10256/26007
url http://hdl.handle.net/10256/26007
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1021/acs.orglett.4c04385
info:eu-repo/semantics/altIdentifier/issn/1523-7060
info:eu-repo/semantics/altIdentifier/eissn/1523-7052
PID2023-147424NB-I00
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023/PID2023-147424NB-I00
dc.rights.none.fl_str_mv Reconeixement 4.0 Internacional
http://creativecommons.org/licenses/by/4.0
info:eu-repo/semantics/openAccess
rights_invalid_str_mv Reconeixement 4.0 Internacional
http://creativecommons.org/licenses/by/4.0
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 6 p.
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society (ACS)
publisher.none.fl_str_mv American Chemical Society (ACS)
dc.source.none.fl_str_mv Organic Letters, 2025, vol. 27, núm. 1, p. 357-362
Articles publicats (D-Q)
Álvarez-Llorente, Nerea Stasyuk, Anton J. Diez-Varga, Alberto Solà i Puig, Miquel Barbero, Héctor Álvarez, Celedonio M. 2025 Multitopic Corannulene-Porphyrin Hosts for Fullerenes: A Three-Layer Scaffold for Precisely Designed Supramolecular Ensembles Organic Letters 27 1 357 362
reponame:Recercat. Dipósit de la Recerca de Catalunya
instname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
instname_str Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
reponame_str Recercat. Dipósit de la Recerca de Catalunya
collection Recercat. Dipósit de la Recerca de Catalunya
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,811543

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