Non-Centrosymmetric Homochiral Supramolecular Polymers of Tetrahedral Subphthalocyanine Molecules
This is the peer reviewed version of the following article: Angewandte Chemie - International Edition 54.8 (2015): 2543-2547, which has been published in final form at http://dx.doi.org/10.1002/anie.201411272. This article may be used for non-commercial purposes in accordance with Wiley Terms and Co...
| Autores: | , , , , , , , |
|---|---|
| Tipo de recurso: | artículo |
| Fecha de publicación: | 2015 |
| País: | España |
| Institución: | Universidad Autónoma de Madrid |
| Repositorio: | Biblos-e Archivo. Repositorio Institucional de la UAM |
| Idioma: | inglés |
| OAI Identifier: | oai:repositorio.uam.es:10486/672460 |
| Acceso en línea: | http://hdl.handle.net/10486/672460 https://dx.doi.org/10.1002/anie.201411272 |
| Access Level: | acceso abierto |
| Palabra clave: | Homochiral aggregates Porphyrinoids Self-assembly Subphthalocyanine Supramolecular polymerization Química |
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Non-Centrosymmetric Homochiral Supramolecular Polymers of Tetrahedral Subphthalocyanine MoleculesGuilleme, JuliaMayoral, María JoséCalbo, JoaquínAragó, JuanViruela, Pedro M.Ortí, EnriqueTorres Cebada, TomásGonzález Rodríguez, DavidHomochiral aggregatesPorphyrinoidsSelf-assemblySubphthalocyanineSupramolecular polymerizationQuímicaThis is the peer reviewed version of the following article: Angewandte Chemie - International Edition 54.8 (2015): 2543-2547, which has been published in final form at http://dx.doi.org/10.1002/anie.201411272. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-ArchivingA combination of spectroscopy (UV/Vis absorption, emission, and circular dichroism), microscopy (AFM and TEM), and computational studies reveal the formation of non-centrosymmetric homochiral columnar subphthalocyanine assemblies. These assemblies form through a cooperative supramolecular polymerization process driven by hydrogen-bonding between amide groups, π-π stacking, and dipolar interactions between axial B-F bondsFunding from MINECO (CTQ2011-24187, CTQ2011-23659, CTQ2011-23659 and 02, CTQ2012-31914, and CTQ2012-35513-C02-01), CAM (S2013/MIT-2841 FOTO-CARBON), GVA (PROMETEO/2012/053)Wiley-VCH VerlagDepartamento de Química OrgánicaFacultad de Ciencias20152015-02-16research articlehttp://purl.org/coar/resource_type/c_2df8fbb1AMhttp://purl.org/coar/version/c_ab4af688f83e57aainfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10486/672460https://dx.doi.org/10.1002/anie.201411272reponame:Biblos-e Archivo. Repositorio Institucional de la UAMinstname:Universidad Autónoma de MadridInglésengopen accesshttp://purl.org/coar/access_right/c_abf2info:eu-repo/semantics/openAccessoai:repositorio.uam.es:10486/6724602026-06-23T12:46:27Z |
| dc.title.none.fl_str_mv |
Non-Centrosymmetric Homochiral Supramolecular Polymers of Tetrahedral Subphthalocyanine Molecules |
| title |
Non-Centrosymmetric Homochiral Supramolecular Polymers of Tetrahedral Subphthalocyanine Molecules |
| spellingShingle |
Non-Centrosymmetric Homochiral Supramolecular Polymers of Tetrahedral Subphthalocyanine Molecules Guilleme, Julia Homochiral aggregates Porphyrinoids Self-assembly Subphthalocyanine Supramolecular polymerization Química |
| title_short |
Non-Centrosymmetric Homochiral Supramolecular Polymers of Tetrahedral Subphthalocyanine Molecules |
| title_full |
Non-Centrosymmetric Homochiral Supramolecular Polymers of Tetrahedral Subphthalocyanine Molecules |
| title_fullStr |
Non-Centrosymmetric Homochiral Supramolecular Polymers of Tetrahedral Subphthalocyanine Molecules |
| title_full_unstemmed |
Non-Centrosymmetric Homochiral Supramolecular Polymers of Tetrahedral Subphthalocyanine Molecules |
| title_sort |
Non-Centrosymmetric Homochiral Supramolecular Polymers of Tetrahedral Subphthalocyanine Molecules |
| dc.creator.none.fl_str_mv |
Guilleme, Julia Mayoral, María José Calbo, Joaquín Aragó, Juan Viruela, Pedro M. Ortí, Enrique Torres Cebada, Tomás González Rodríguez, David |
| author |
Guilleme, Julia |
| author_facet |
Guilleme, Julia Mayoral, María José Calbo, Joaquín Aragó, Juan Viruela, Pedro M. Ortí, Enrique Torres Cebada, Tomás González Rodríguez, David |
| author_role |
author |
| author2 |
Mayoral, María José Calbo, Joaquín Aragó, Juan Viruela, Pedro M. Ortí, Enrique Torres Cebada, Tomás González Rodríguez, David |
| author2_role |
author author author author author author author |
| dc.contributor.none.fl_str_mv |
Departamento de Química Orgánica Facultad de Ciencias |
| dc.subject.none.fl_str_mv |
Homochiral aggregates Porphyrinoids Self-assembly Subphthalocyanine Supramolecular polymerization Química |
| topic |
Homochiral aggregates Porphyrinoids Self-assembly Subphthalocyanine Supramolecular polymerization Química |
| description |
This is the peer reviewed version of the following article: Angewandte Chemie - International Edition 54.8 (2015): 2543-2547, which has been published in final form at http://dx.doi.org/10.1002/anie.201411272. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving |
| publishDate |
2015 |
| dc.date.none.fl_str_mv |
2015 2015-02-16 |
| dc.type.none.fl_str_mv |
research article http://purl.org/coar/resource_type/c_2df8fbb1 AM http://purl.org/coar/version/c_ab4af688f83e57aa |
| dc.type.openaire.fl_str_mv |
info:eu-repo/semantics/article |
| format |
article |
| dc.identifier.none.fl_str_mv |
http://hdl.handle.net/10486/672460 https://dx.doi.org/10.1002/anie.201411272 |
| url |
http://hdl.handle.net/10486/672460 https://dx.doi.org/10.1002/anie.201411272 |
| dc.language.none.fl_str_mv |
Inglés eng |
| language_invalid_str_mv |
Inglés |
| language |
eng |
| dc.rights.none.fl_str_mv |
open access http://purl.org/coar/access_right/c_abf2 |
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info:eu-repo/semantics/openAccess |
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open access http://purl.org/coar/access_right/c_abf2 |
| eu_rights_str_mv |
openAccess |
| dc.format.none.fl_str_mv |
application/pdf |
| dc.publisher.none.fl_str_mv |
Wiley-VCH Verlag |
| publisher.none.fl_str_mv |
Wiley-VCH Verlag |
| dc.source.none.fl_str_mv |
reponame:Biblos-e Archivo. Repositorio Institucional de la UAM instname:Universidad Autónoma de Madrid |
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Universidad Autónoma de Madrid |
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Biblos-e Archivo. Repositorio Institucional de la UAM |
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Biblos-e Archivo. Repositorio Institucional de la UAM |
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