Past, present and future global influence and technological applications of iron-bearing metastable nanominerals

Iron-bearing nanominerals such as ferrihydrite, schwertmannite, and green rust behave as metastable precursors leading to the formation of more thermodynamically stable iron mineral phases (e.g., jarosite, goethite, hematite, and magnetite). However, this transformation may last from days to tens or...

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Detalles Bibliográficos
Autores: Caraballo Monge, Manuel Antonio, Asta, M. P., Perez, Jeffrey Paulo H., Hochella Jr., Michel F.
Tipo de recurso: artículo
Fecha de publicación:2021
País:España
Institución:Universidad de Huelva (UHU)
Repositorio:Arias Montano. Repositorio Institucional de la Universidad de Huelva
Idioma:inglés
OAI Identifier:oai:ariasmontano.uhu.es:10272/20448
Acceso en línea:http://hdl.handle.net/10272/20448
Access Level:acceso abierto
Palabra clave:Ferrihydrite
Schwertmannite
Green rust
Nanotechnology
Nanogeosciences
Descripción
Sumario:Iron-bearing nanominerals such as ferrihydrite, schwertmannite, and green rust behave as metastable precursors leading to the formation of more thermodynamically stable iron mineral phases (e.g., jarosite, goethite, hematite, and magnetite). However, this transformation may last from days to tens or even hundreds of years, making them the most predominant iron-bearing minerals at environmental conditions and at the human time scale. The present review characterizes ferrihydrite, schwertmannite, and green rust nanominerals according to their main physical and chemical properties, and at both nano- and mesoscales. It also presents a comprehensive review of the multiple past and present Earth environments where these nanominerals have played, and still play, a pivotal role in the geochemistry, mineralogy and environmental nanogeosciences of these environments. Finally, the present and future technological applications of these nanominerals as well as their role in the generation of a more sustainable human- Earth relationship is discussed, with a special emphasis on their use in new circular economies and green based technologies.