Multitopic corannulene–porphyrin hosts for fullerenes: a three-layer scaffold for precisely designed supramolecular ensembles

Producción Científica

Detalles Bibliográficos
Autores: Álvarez Llorente, Nerea, Stasyuk, Anton J., Diez De La Varga, Alberto, Ferrero, Sergio, Solà, Miquel, Barbero San Juan, Héctor, Álvarez González, Celedonio Manuel
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2024
País:España
Institución:Universidad de Valladolid
Repositorio:UVaDOC. Repositorio Documental de la Universidad de Valladolid
OAI Identifier:oai:uvadoc.uva.es:10324/75064
Acceso en línea:https://doi.org/10.1021/acs.orglett.4c04385
https://uvadoc.uva.es/handle/10324/75064
Access Level:acceso abierto
Palabra clave:2303 Química Inorgánica
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spelling Multitopic corannulene–porphyrin hosts for fullerenes: a three-layer scaffold for precisely designed supramolecular ensemblesÁlvarez Llorente, NereaStasyuk, Anton J.Diez De La Varga, AlbertoFerrero, SergioSolà, MiquelBarbero San Juan, HéctorÁlvarez González, Celedonio Manuel2303 Química InorgánicaProducción CientíficaA method to synthesize cofacial dimeric porphyrins bearing eight corannulene units has been developed. It relies on the stability of octahedral CO-capped Ru(II) complexes linked by N-donor ligands. This specific arrangement provides an optimal scaffold to accommodate fullerenes by imposing corannulene groups at a precise distance and relative orientation. Their capabilities for C60 recognition have been thoroughly assessed, revealing that each system can encapsulate up to four guests, giving rise to a compact supramolecular van der Waals complex echoing a discrete donor–acceptor–donor trilayer offering significant potential properties for further exploitation.Ministerio de Ciencia e Innovación (PID2021-124691NB-I00, RED2022-14939-T, PID2023-147424NB-I00, CEX 2021-001202-M)Generalitat de Catalunya-Conselleria de Recerca i Universitats (2021SGR623)PLGrid-Computational Grants (PLG/2023/016841)Unión Europea-NextGenerationEU (María Zambrano CONVREC-2021-264)Fundación Ramón Areces (contrato posdoctoral)Universidad de Valladolid-Banco Santander (contrato predoctoral)ACS (American Chemical Society)2024info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfhttps://doi.org/10.1021/acs.orglett.4c04385https://uvadoc.uva.es/handle/10324/75064reponame:UVaDOC. Repositorio Documental de la Universidad de Valladolidinstname:Universidad de ValladolidIngléshttps://pubs.acs.org/doi/10.1021/acs.orglett.4c04385info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by/4.0/oai:uvadoc.uva.es:10324/750642026-06-13T12:44:47Z
dc.title.none.fl_str_mv Multitopic corannulene–porphyrin hosts for fullerenes: a three-layer scaffold for precisely designed supramolecular ensembles
title Multitopic corannulene–porphyrin hosts for fullerenes: a three-layer scaffold for precisely designed supramolecular ensembles
spellingShingle Multitopic corannulene–porphyrin hosts for fullerenes: a three-layer scaffold for precisely designed supramolecular ensembles
Álvarez Llorente, Nerea
2303 Química Inorgánica
title_short Multitopic corannulene–porphyrin hosts for fullerenes: a three-layer scaffold for precisely designed supramolecular ensembles
title_full Multitopic corannulene–porphyrin hosts for fullerenes: a three-layer scaffold for precisely designed supramolecular ensembles
title_fullStr Multitopic corannulene–porphyrin hosts for fullerenes: a three-layer scaffold for precisely designed supramolecular ensembles
title_full_unstemmed Multitopic corannulene–porphyrin hosts for fullerenes: a three-layer scaffold for precisely designed supramolecular ensembles
title_sort Multitopic corannulene–porphyrin hosts for fullerenes: a three-layer scaffold for precisely designed supramolecular ensembles
dc.creator.none.fl_str_mv Álvarez Llorente, Nerea
Stasyuk, Anton J.
Diez De La Varga, Alberto
Ferrero, Sergio
Solà, Miquel
Barbero San Juan, Héctor
Álvarez González, Celedonio Manuel
author Álvarez Llorente, Nerea
author_facet Álvarez Llorente, Nerea
Stasyuk, Anton J.
Diez De La Varga, Alberto
Ferrero, Sergio
Solà, Miquel
Barbero San Juan, Héctor
Álvarez González, Celedonio Manuel
author_role author
author2 Stasyuk, Anton J.
Diez De La Varga, Alberto
Ferrero, Sergio
Solà, Miquel
Barbero San Juan, Héctor
Álvarez González, Celedonio Manuel
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv 2303 Química Inorgánica
topic 2303 Química Inorgánica
description Producción Científica
publishDate 2024
dc.date.none.fl_str_mv 2024
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv https://doi.org/10.1021/acs.orglett.4c04385
https://uvadoc.uva.es/handle/10324/75064
url https://doi.org/10.1021/acs.orglett.4c04385
https://uvadoc.uva.es/handle/10324/75064
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv https://pubs.acs.org/doi/10.1021/acs.orglett.4c04385
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by/4.0/
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by/4.0/
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv ACS (American Chemical Society)
publisher.none.fl_str_mv ACS (American Chemical Society)
dc.source.none.fl_str_mv reponame:UVaDOC. Repositorio Documental de la Universidad de Valladolid
instname:Universidad de Valladolid
instname_str Universidad de Valladolid
reponame_str UVaDOC. Repositorio Documental de la Universidad de Valladolid
collection UVaDOC. Repositorio Documental de la Universidad de Valladolid
repository.name.fl_str_mv
repository.mail.fl_str_mv
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