Determination of uranium and thorium isotopes in NORM materials in the ceramic industry by using alpha-particle spectrometry

[EN] A radiochemical procedure has been developed for the quantification of uranium and thorium isotopes in NORM samples from the ceramic industry, such as zirconium sands, zirconium flours, micronized zircon, pigments and personal aerosol filters. The method is based on a fusion pretreatment with b...

Descripción completa

Detalles Bibliográficos
Autores: Sevilla, A. J., Ortiz Moragón, Josefina, Sáez-Muñoz, Marina|||0000-0003-0180-7167, Pérez-Baeza, Mireia, Martorell Alsina, Sebastián Salvador|||0000-0003-1706-4740
Tipo de recurso: artículo
Fecha de publicación:2024
País:España
Institución:Universitat Politècnica de València (UPV)
Repositorio:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
Idioma:inglés
OAI Identifier:oai:riunet.upv.es:10251/209163
Acceso en línea:https://riunet.upv.es/handle/10251/209163
Access Level:acceso abierto
Palabra clave:NORM
Zirconium
Ceramic industry
Uranium
Thorium
Alpha-particle spectrometry
INGENIERIA NUCLEAR
Descripción
Sumario:[EN] A radiochemical procedure has been developed for the quantification of uranium and thorium isotopes in NORM samples from the ceramic industry, such as zirconium sands, zirconium flours, micronized zircon, pigments and personal aerosol filters. The method is based on a fusion pretreatment with borate salts, a separation with anion exchange resins and alpha-particle spectrometry measurement. This method is an alternative to gamma spectrometry when the amount of sample is extremely small (2-10 mg) as in the case of aerosol filters, or there is no secular equilibrium in the 238U and 232Th chains, as in the ceramic pigments. The method has been validated with different ceramic materials and the comparison of the results with gamma measurements. Its reproducibility was also checked with different sample masses.