Functional aromatic polyamides for the preparation of coated fibres as smart labels for the visual detection of biogenic amine vapours and fish spoilage

We have prepared high-performance functional aromatic polyamides with sensory pendant groups toward amines. These polymers are colourless. The pendant groups have bromonaphthalimide motifs that react with amines rendering coloured arylamines by nucleophilic aromatic substitution of the halide. Thus,...

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Autores: González Ceballos, Lara, Melero Gil, Beatriz, Trigo López, Miriam, Vallejos Calzada, Saúl, Muñoz Santamaría, María Asunción, García García, Félix Clemente, Fernández Muiño, Miguel Ángel, Sancho Ortiz, María Teresa, García Pérez, José Miguel
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2020
País:España
Institución:Universidad de Burgos (UBU)
Repositorio:Repositorio Institucional de la Universidad de Burgos (RIUBU)
OAI Identifier:oai:riubu.ubu.es:10259/5198
Acceso en línea:http://hdl.handle.net/10259/5198
Access Level:acceso abierto
Palabra clave:Amine sensors
Biogenic amines
Polymer chemosensors
Smart labels
Fish spoilage
Química
Chemistry
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spelling Functional aromatic polyamides for the preparation of coated fibres as smart labels for the visual detection of biogenic amine vapours and fish spoilageGonzález Ceballos, LaraMelero Gil, BeatrizTrigo López, MiriamVallejos Calzada, SaúlMuñoz Santamaría, María AsunciónGarcía García, Félix ClementeFernández Muiño, Miguel ÁngelSancho Ortiz, María TeresaGarcía Pérez, José MiguelAmine sensorsBiogenic aminesPolymer chemosensorsSmart labelsFish spoilageQuímicaChemistryWe have prepared high-performance functional aromatic polyamides with sensory pendant groups toward amines. These polymers are colourless. The pendant groups have bromonaphthalimide motifs that react with amines rendering coloured arylamines by nucleophilic aromatic substitution of the halide. Thus, these materials are colorimetric sensors toward amines. In the interest of saving costs, while having a sensory material with a high specific surface, cotton fabrics were coated, in order to render coated fibres as smart colorimetric labels toward amines. Moreover, as fish spoilage by microorganism increases the biogenic amines in food, we have applied the smart labels to visually follow the food spoilage. Also, a picture taken to the films allowed to obtain, in seconds, the digital colour definition parameters (RGB) that were correlated with the results of expensive and time-consuming conventional techniques used to obtain relevant food quality data, such as total amine concentration (treatment of the sample and HPLC), colony-forming unit (microbiological assays), total volatile basic nitrogen (TVB-N), and organoleptic test (sensory test). The smart labels are inexpensive, granting in seconds the visual qualitative evaluation of the food quality, or even quantitative, and they comply with the European food contact materials regulation.FEDER (Fondo Europeo de Desarrollo Regional), and both the Spanish Ministerio de Economía, Industsria y Competitividad (MAT2017-84501-R) and the Consejería de Educación—Junta de Castilla y León (BU061U16)Elsevier202020202020info:eu-repo/semantics/articleinfo:eu-repo/semantics/acceptedVersionapplication/pdfhttp://hdl.handle.net/10259/5198reponame:Repositorio Institucional de la Universidad de Burgos (RIUBU)instname:Universidad de Burgos (UBU)InglésSensors and Actuators B: Chemical. 2020, V. 304, 127249https://doi.org/10.1016/j.snb.2019.127249info:eu-repo/grantAgreement/MINECO/MAT2017-84501-R/info:eu-repo/grantAgreement/JCyL/BU061U16/http://creativecommons.org/licenses/by-nc-nd/4.0/Attribution-NonCommercial-NoDerivatives 4.0 Internacionalinfo:eu-repo/semantics/openAccessoai:riubu.ubu.es:10259/51982026-05-28T07:56:11Z
dc.title.none.fl_str_mv Functional aromatic polyamides for the preparation of coated fibres as smart labels for the visual detection of biogenic amine vapours and fish spoilage
title Functional aromatic polyamides for the preparation of coated fibres as smart labels for the visual detection of biogenic amine vapours and fish spoilage
spellingShingle Functional aromatic polyamides for the preparation of coated fibres as smart labels for the visual detection of biogenic amine vapours and fish spoilage
González Ceballos, Lara
Amine sensors
Biogenic amines
Polymer chemosensors
Smart labels
Fish spoilage
Química
Chemistry
title_short Functional aromatic polyamides for the preparation of coated fibres as smart labels for the visual detection of biogenic amine vapours and fish spoilage
title_full Functional aromatic polyamides for the preparation of coated fibres as smart labels for the visual detection of biogenic amine vapours and fish spoilage
title_fullStr Functional aromatic polyamides for the preparation of coated fibres as smart labels for the visual detection of biogenic amine vapours and fish spoilage
title_full_unstemmed Functional aromatic polyamides for the preparation of coated fibres as smart labels for the visual detection of biogenic amine vapours and fish spoilage
title_sort Functional aromatic polyamides for the preparation of coated fibres as smart labels for the visual detection of biogenic amine vapours and fish spoilage
dc.creator.none.fl_str_mv González Ceballos, Lara
Melero Gil, Beatriz
Trigo López, Miriam
Vallejos Calzada, Saúl
Muñoz Santamaría, María Asunción
García García, Félix Clemente
Fernández Muiño, Miguel Ángel
Sancho Ortiz, María Teresa
García Pérez, José Miguel
author González Ceballos, Lara
author_facet González Ceballos, Lara
Melero Gil, Beatriz
Trigo López, Miriam
Vallejos Calzada, Saúl
Muñoz Santamaría, María Asunción
García García, Félix Clemente
Fernández Muiño, Miguel Ángel
Sancho Ortiz, María Teresa
García Pérez, José Miguel
author_role author
author2 Melero Gil, Beatriz
Trigo López, Miriam
Vallejos Calzada, Saúl
Muñoz Santamaría, María Asunción
García García, Félix Clemente
Fernández Muiño, Miguel Ángel
Sancho Ortiz, María Teresa
García Pérez, José Miguel
author2_role author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv Amine sensors
Biogenic amines
Polymer chemosensors
Smart labels
Fish spoilage
Química
Chemistry
topic Amine sensors
Biogenic amines
Polymer chemosensors
Smart labels
Fish spoilage
Química
Chemistry
description We have prepared high-performance functional aromatic polyamides with sensory pendant groups toward amines. These polymers are colourless. The pendant groups have bromonaphthalimide motifs that react with amines rendering coloured arylamines by nucleophilic aromatic substitution of the halide. Thus, these materials are colorimetric sensors toward amines. In the interest of saving costs, while having a sensory material with a high specific surface, cotton fabrics were coated, in order to render coated fibres as smart colorimetric labels toward amines. Moreover, as fish spoilage by microorganism increases the biogenic amines in food, we have applied the smart labels to visually follow the food spoilage. Also, a picture taken to the films allowed to obtain, in seconds, the digital colour definition parameters (RGB) that were correlated with the results of expensive and time-consuming conventional techniques used to obtain relevant food quality data, such as total amine concentration (treatment of the sample and HPLC), colony-forming unit (microbiological assays), total volatile basic nitrogen (TVB-N), and organoleptic test (sensory test). The smart labels are inexpensive, granting in seconds the visual qualitative evaluation of the food quality, or even quantitative, and they comply with the European food contact materials regulation.
publishDate 2020
dc.date.none.fl_str_mv 2020
2020
2020
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/acceptedVersion
format article
status_str acceptedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10259/5198
url http://hdl.handle.net/10259/5198
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv Sensors and Actuators B: Chemical. 2020, V. 304, 127249
https://doi.org/10.1016/j.snb.2019.127249
info:eu-repo/grantAgreement/MINECO/MAT2017-84501-R/
info:eu-repo/grantAgreement/JCyL/BU061U16/
dc.rights.none.fl_str_mv http://creativecommons.org/licenses/by-nc-nd/4.0/
Attribution-NonCommercial-NoDerivatives 4.0 Internacional
info:eu-repo/semantics/openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by-nc-nd/4.0/
Attribution-NonCommercial-NoDerivatives 4.0 Internacional
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:Repositorio Institucional de la Universidad de Burgos (RIUBU)
instname:Universidad de Burgos (UBU)
instname_str Universidad de Burgos (UBU)
reponame_str Repositorio Institucional de la Universidad de Burgos (RIUBU)
collection Repositorio Institucional de la Universidad de Burgos (RIUBU)
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15.301603

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