Modelización reológica mediante Cross-WLF de un nuevo material compuesto elaborado con bioPE y Thyme

[EN] Increased environmental awareness is driving the continuous search for new eco-friendly materials. Within the category of Wood Plastics Composites (WPC), a new "Green Composite" is proposed, whose matrix is a bio-polyethylene (bioPE) obtained from sugar cane and whose load, wi...

ver descrição completa

Detalhes bibliográficos
Autores: Montanes, Nestor|||0000-0001-6070-127X, Balart, Rafael|||0000-0001-5670-7126, Fombuena, Vicent|||0000-0001-7266-6205, Fenollar, Octavio|||0000-0003-4323-7414, Boronat, Teodomiro|||0000-0002-2144-2874
Formato: artículo
Fecha de publicación:2018
País:España
Recursos:Universitat Politècnica de València (UPV)
Repositorio:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
Idioma:español
OAI Identifier:oai:riunet.upv.es:10251/125202
Acesso em linha:https://riunet.upv.es/handle/10251/125202
Access Level:acceso abierto
Palavra-chave:Reología
Viscosidad
Green Composite
Cross-WLF
INGENIERIA DE LOS PROCESOS DE FABRICACION
CIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA
INGENIERIA QUIMICA
Descrição
Resumo:[EN] Increased environmental awareness is driving the continuous search for new eco-friendly materials. Within the category of Wood Plastics Composites (WPC), a new "Green Composite" is proposed, whose matrix is a bio-polyethylene (bioPE) obtained from sugar cane and whose load, with reinforcing properties due to its fibrous structure, is Thyme, as a residue from the distillation of a liquor manufactured in a local company. Load concentrations of 10%, 30% and 50% %w have been studied. Since the polymers are processed in the molten state and the loads influence their visco-elastic behavior, it is necessary to know the rheological behavior of these new compounds, in order to evaluate their processability. The melt polymer viscosity is very sensitive to the temperature and the shear rate at which it is being processed. The Cross-WLF model, based on the experimental results obtained with a capillary rheometer, describes the rheological behavior of the materials, thus enabling the determination of the viscosity of these new bio-compounds under different conditions than those tested. In this way the processability of these new materials can be evaluated.