Recognition of peptidoglycan and beta-lactam antibiotics by the extracellular domain of the Ser/Thr protein kinase StkP from Streptococcus pneumoniae

The eukaryotic-type serine/threonine kinase StkP from Streptococcus pneumoniae is an important signal-transduction element that regulates the expression of numerous pneumococcal genes. We have expressed the extracellular C-terminal domain of StkP kinase (C-StkP), elaborated a three-dimensional struc...

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Detalhes bibliográficos
Autores: Maestro García-Donas, María Beatriz, Novakova, Linda, Hesek, Dusan, Lee, Mijoo, Leyva, Eduardo, Mobashery, Shahriar, Sanz, Jesús, Branny, Pavel
Formato: artículo
Fecha de publicación:2010
País:España
Recursos:Universidad Complutense de Madrid (UCM)
Repositorio:Docta Complutense
Idioma:inglés
OAI Identifier:oai:docta.ucm.es:20.500.14352/93182.2
Acesso em linha:https://hdl.handle.net/20.500.14352/93182.2
Access Level:acceso abierto
Palavra-chave:577.1
Signal transduction
Penicillin-binding protein and Ser/Thr
Protein kinase-associated domain
Peptidoglycanb-Lactam antibiotics
Protein structure
Streptococcus pneumoniae
Bioquímica (Química)
2403 Bioquímica
Descrição
Resumo:The eukaryotic-type serine/threonine kinase StkP from Streptococcus pneumoniae is an important signal-transduction element that regulates the expression of numerous pneumococcal genes. We have expressed the extracellular C-terminal domain of StkP kinase (C-StkP), elaborated a three-dimensional structural model and performed a spectroscopical characterization of its structure and stability. Biophysical experiments show that C-StkP binds to synthetic samples of the cell wall peptidoglycan (PGN) and to β-lactam antibiotics, which mimic the terminal portions of the PGN stem peptide. This is the first experimental report on the recognition of a minimal PGN unit by a PASTA-containing kinase, suggesting that non-crosslinked PGN may act as a signal for StkP function and pointing to this protein as an interesting target for β-lactam antibiotics.