Organic-based field effect transistors for protein detection fabricated by inkjet-printing

Biosensors based on Organic Field-Effect Transistors (OFETs) have attracted increasing attention due to the possibility of rapid, label-free, and inexpensive detection. Among all the different possibilities, inkjet-printed top-gate organic Field Effect Transistors-Based Biosensors (BioFETs) using a...

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Detalles Bibliográficos
Autores: Martínez-Domingo, Carme|||0000-0002-1897-5362, Conti, Silvia, De La Escosura-Muñiz, Alfredo|||0000-0002-9600-0253, Terés, Lluís, Merkoçi, Arben|||0000-0003-2486-8085, Ramon, Eloi|||0000-0001-9974-8112
Tipo de recurso: artículo
Fecha de publicación:2020
País:España
Institución:Universitat Autònoma de Barcelona
Repositorio:Dipòsit Digital de Documents de la UAB
Idioma:inglés
OAI Identifier:oai:ddd.uab.cat:236006
Acceso en línea:https://ddd.uab.cat/record/236006
https://dx.doi.org/urn:doi:10.1016/j.orgel.2020.105794
Access Level:acceso abierto
Palabra clave:Organic electronics
Inkjet-printing
Thin-film transistor
Surface functionalization
Descripción
Sumario:Biosensors based on Organic Field-Effect Transistors (OFETs) have attracted increasing attention due to the possibility of rapid, label-free, and inexpensive detection. Among all the different possibilities, inkjet-printed top-gate organic Field Effect Transistors-Based Biosensors (BioFETs) using a polymeric gate insulator have been seldom reported. In this work, a systematic investigation in terms of topographical and electrical characterization was carried out in order to find the optimal fabrication process for obtaining a reliable polymer insulator. Previous studies have demonstrated that the best electrical performance arises from the use of the perfluoropolymer Cytop™[12,13,14]. Consequently, a simple immobilization protocol was used to ensure the proper attachment of a model biomolecule onto the Cytop's hydrophobic surface whilst keeping its remarkable insulating properties with gate current in the range of dozens of pico-amperes. The top-gate inkjet-printed BioFETs presented in this study operate at threshold voltages in the range of 1-2 V and show durability even when exposed to oxygen plasma, wet amine functionalization treatments, and aqueous media. As a preliminary application, the inkjet-printed top-gate BioFETs is used for monitoring an immunoreaction by measuring changes in the drain current, paving the way for further use of this device in the immunosensing field.