Introducing the aziridination of fluorinated olefins by metal‐catalyzed nitrene transfer

After decades of development of the metal-catalyzed nitrene transfer reactions to olefins, examples involving the use of fluorinated olefins is yet unknown, despite the current importance of fluorocompounds. Herein we describe the use of copper- and silver-based catalysts for a general protocol that...

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Detalles Bibliográficos
Autores: Pérez-Ruíz, Jorge, Rosales Martínez, Antonio, Pérez, Pedro J., Díaz-Requejo, M. Mar
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2025
País:España
Institución:Universidad de Sevilla (US)
Repositorio:idUS. Depósito de Investigación de la Universidad de Sevilla
OAI Identifier:oai:idus.us.es:11441/175024
Acceso en línea:https://hdl.handle.net/11441/175024
https://doi.org/10.1002/anie.202419188
Access Level:acceso abierto
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spelling Introducing the aziridination of fluorinated olefins by metal‐catalyzed nitrene transferPérez-Ruíz, JorgeRosales Martínez, AntonioPérez, Pedro J.Díaz-Requejo, M. MarAfter decades of development of the metal-catalyzed nitrene transfer reactions to olefins, examples involving the use of fluorinated olefins is yet unknown, despite the current importance of fluorocompounds. Herein we describe the use of copper- and silver-based catalysts for a general protocol that converts α- or β-fluoro olefins into the corresponding aziridines in high yields.WileyIngeniería QuímicaMinisterio de Ciencia e Innovación (MICIN). EspañaJunta de AndalucíaUniversidad de HuelvaUniversidad de Sevilla2025info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfapplication/pdfhttps://hdl.handle.net/11441/175024https://doi.org/10.1002/anie.202419188reponame:idUS. Depósito de Investigación de la Universidad de Sevillainstname:Universidad de Sevilla (US)InglésAngewandte Chemie-International Edition, 64 (23), e202419188.PID2020-113797RB-C21PID2023-146946NB-I00P20-00348UHU-202016REC-B19989-1REC-B19989-2https://doi.org/10.1002/anie.202419188info:eu-repo/semantics/openAccessoai:idus.us.es:11441/1750242026-06-17T12:51:07Z
dc.title.none.fl_str_mv Introducing the aziridination of fluorinated olefins by metal‐catalyzed nitrene transfer
title Introducing the aziridination of fluorinated olefins by metal‐catalyzed nitrene transfer
spellingShingle Introducing the aziridination of fluorinated olefins by metal‐catalyzed nitrene transfer
Pérez-Ruíz, Jorge
title_short Introducing the aziridination of fluorinated olefins by metal‐catalyzed nitrene transfer
title_full Introducing the aziridination of fluorinated olefins by metal‐catalyzed nitrene transfer
title_fullStr Introducing the aziridination of fluorinated olefins by metal‐catalyzed nitrene transfer
title_full_unstemmed Introducing the aziridination of fluorinated olefins by metal‐catalyzed nitrene transfer
title_sort Introducing the aziridination of fluorinated olefins by metal‐catalyzed nitrene transfer
dc.creator.none.fl_str_mv Pérez-Ruíz, Jorge
Rosales Martínez, Antonio
Pérez, Pedro J.
Díaz-Requejo, M. Mar
author Pérez-Ruíz, Jorge
author_facet Pérez-Ruíz, Jorge
Rosales Martínez, Antonio
Pérez, Pedro J.
Díaz-Requejo, M. Mar
author_role author
author2 Rosales Martínez, Antonio
Pérez, Pedro J.
Díaz-Requejo, M. Mar
author2_role author
author
author
dc.contributor.none.fl_str_mv Ingeniería Química
Ministerio de Ciencia e Innovación (MICIN). España
Junta de Andalucía
Universidad de Huelva
Universidad de Sevilla
description After decades of development of the metal-catalyzed nitrene transfer reactions to olefins, examples involving the use of fluorinated olefins is yet unknown, despite the current importance of fluorocompounds. Herein we describe the use of copper- and silver-based catalysts for a general protocol that converts α- or β-fluoro olefins into the corresponding aziridines in high yields.
publishDate 2025
dc.date.none.fl_str_mv 2025
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv https://hdl.handle.net/11441/175024
https://doi.org/10.1002/anie.202419188
url https://hdl.handle.net/11441/175024
https://doi.org/10.1002/anie.202419188
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv Angewandte Chemie-International Edition, 64 (23), e202419188.
PID2020-113797RB-C21
PID2023-146946NB-I00
P20-00348
UHU-202016
REC-B19989-1
REC-B19989-2
https://doi.org/10.1002/anie.202419188
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Wiley
publisher.none.fl_str_mv Wiley
dc.source.none.fl_str_mv reponame:idUS. Depósito de Investigación de la Universidad de Sevilla
instname:Universidad de Sevilla (US)
instname_str Universidad de Sevilla (US)
reponame_str idUS. Depósito de Investigación de la Universidad de Sevilla
collection idUS. Depósito de Investigación de la Universidad de Sevilla
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15.81155

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