A facile method to obtain hydrophilic-hydrophobic hyaluronic acid- polylactic acid bilayer films

[EN] Fostering cell attachment is essential for tissue engineering. However, unwanted cellular interactions increase the risk of post-operative adhesions which can hinder tissue regeneration. Thus, cell-adhesion-promoting and cell-adhesion-inhibitory functions need to be regulated simultaneously. We...

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Detalles Bibliográficos
Autores: Navarro-Páez, Francisco|||0000-0002-4383-3681, Martínez-Férriz, Arantxa|||0000-0001-7193-2575, Martínez-Ramos, Cristina|||0000-0002-6540-4714, Monleón Pradas, Manuel|||0000-0001-6457-0414
Tipo de recurso: artículo
Fecha de publicación:2025
País:España
Institución:Universitat Politècnica de València (UPV)
Repositorio:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
Idioma:inglés
OAI Identifier:oai:riunet.upv.es:10251/220024
Acceso en línea:https://riunet.upv.es/handle/10251/220024
Access Level:acceso abierto
Palabra clave:Polylactic acid
Hyaluronic acid
Cell adhesion prevention
Schwann cells
Descripción
Sumario:[EN] Fostering cell attachment is essential for tissue engineering. However, unwanted cellular interactions increase the risk of post-operative adhesions which can hinder tissue regeneration. Thus, cell-adhesion-promoting and cell-adhesion-inhibitory functions need to be regulated simultaneously. We develop a stably joined bilayer film composed of a thin polylactic acid film (cell interactive side) obtained by solvent casting coated with hyaluronic acid (cell antifouling side) crosslinked with divinyl sulphone, seeking to reduce post-operative adhesions after surgery. Both layers were bonded together by a biocompatible nitrocellulose-base adhesive forming a long-term stable bilayer due to the reaction between their chemical groups and the formation of a semi-interpenetrating polymeric network on the amorphous regions of the polylactic acid film. A thorough physicochemical characterisation (morphology, composition, swelling ratio and stability) of this novel type of scaffold was carried out to ensure a comprehensive understanding of its structural properties and performance characteristics. Schwann cell culture on the bilayer film proved that the polylactic acid surface was cell-friendly and promoted cell attachment and proliferation whereas the hyaluronic acid surface prevented initial cell adhesion.