A microfluidic flow-through electrochemical reactor for wastewater treatment: a proof-of-concept

In this work, a microfluidic flow-through electrochemical reactor for wastewater treatment is presented which simultaneously minimizes ohmic drop and mass transfer limitations, two of the most important bottlenecks in electrochemical wastewater treatment. A proof-of-concept comparison versus a state...

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Detalles Bibliográficos
Autores: Pérez Serrano, José Fernando, Llanos López, Javier, Sáez Jiménez, Cristina, López Gómez, Conrado, Cañizares Cañizares, Pablo, Rodrigo Rodrigo, Manuel Andrés
Tipo de recurso: artículo
Fecha de publicación:2017
País:España
Institución:Universidad de Castilla-La Mancha
Repositorio:RUIdeRA. Repositorio Institucional de la UCLM
OAI Identifier:oai:ruidera.uclm.es:10578/17611
Acceso en línea:http://hdl.handle.net/10578/17611
Access Level:acceso abierto
Palabra clave:Electrochemical processes
Reactor design
Microfluidic
Flow-through
3D electrodes
Diamond anodes
Procesos electroquímicos
Diseño del reactor
Microfluido
Flujo continuo
Electrodos 3D
Ánodos de diamante
Descripción
Sumario:In this work, a microfluidic flow-through electrochemical reactor for wastewater treatment is presented which simultaneously minimizes ohmic drop and mass transfer limitations, two of the most important bottlenecks in electrochemical wastewater treatment. A proof-of-concept comparison versus a state-of-the-art flow-by commercial reactor revealed that the proposed reactor greatly outperforms the commercial system. The novel system requires only 2.4 Ah dm-3 (vs. 11.4 Ah dm-3) and 12.5 kWh m-3 (vs. 15 75.0 kWh m-3) to completely mineralize 100 mg dm-3 of clopyralid spiked in a low- conductive (1 mS cm-1) matrix with both systems using diamond anodes. The microfluidic flow-through configuration represents a promising approach to the development of cost-effective electrochemical technologies for wastewater treatment.