[2,6-Bis(2-pyrimidinylthiomethyl)pyridine]dichlorocopper(II) methanol solvate

In the title compound [CuCl2(C15H13N5S2].CH3OH, the Cu2+ ion has square-pyramidal coordination geometry. The basal plane of the pyramid is formed by two Cl- ions, one pyridine N atom and one pyrimidine N atom. The fifth coordination site is occupied by the S atom of a thiomethyl group. The methanol...

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Detalhes bibliográficos
Autores: Kivekäs, Raikko, Sillanpää, Reijo, Escriche, Lluís|||0000-0003-2562-5034, Sánchez-Castelló, G., Casabó i Gispert, Jaume
Tipo de documento: artigo
Data de publicação:1994
País:España
Recursos:Universitat Autònoma de Barcelona
Repositório:Dipòsit Digital de Documents de la UAB
Idioma:inglês
OAI Identifier:oai:ddd.uab.cat:27744
Acesso em linha:https://ddd.uab.cat/record/27744
https://dx.doi.org/urn:doi:10.1107/S0108270193013629
Access Level:Acceso aberto
Palavra-chave:Cristal·lografia
Crystallography
Descrição
Resumo:In the title compound [CuCl2(C15H13N5S2].CH3OH, the Cu2+ ion has square-pyramidal coordination geometry. The basal plane of the pyramid is formed by two Cl- ions, one pyridine N atom and one pyrimidine N atom. The fifth coordination site is occupied by the S atom of a thiomethyl group. The methanol molecule occupies an otherwise empty space in the structure.