Alkylidene Transfer from Monochloroalkylmercury(II) Compounds to Aromatic Amines; Selective C-Alkylation
α,α-Diarylalkane derivatives have been synthesized from monochloroalkylmercury(II) compounds in a non-carbenoid alkylidene transfer reaction which takes place selectively on the aromatic ring. A mechanism is suggested for this process. Intermediate products are prepared by alternative routes to asce...
| Autores: | , , , |
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| Tipo de recurso: | artículo |
| Estado: | Versión publicada |
| Fecha de publicación: | 1980 |
| País: | España |
| Institución: | Universidad de La Rioja (UR) |
| Repositorio: | RIUR. Repositorio Institucional de la Universidad de La Rioja |
| OAI Identifier: | oai:portal.dialnet.es:doc/5bbc68b4b750603269e80df5 |
| Acceso en línea: | https://investigacion.unirioja.es/documentos/5bbc68b4b750603269e80df5 |
| Access Level: | acceso abierto |
| Sumario: | α,α-Diarylalkane derivatives have been synthesized from monochloroalkylmercury(II) compounds in a non-carbenoid alkylidene transfer reaction which takes place selectively on the aromatic ring. A mechanism is suggested for this process. Intermediate products are prepared by alternative routes to ascertain their participation in the course of the reaction. As a consequence, two different aryl groups can be successively incorporated into the alkane molecule. |
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