Interfering Plasmons in Coupled Nanoresonators to Boost Light Localization and SERS

[EN] Plasmonic self-assembled nanocavities are ideal platforms for extreme light localization as they deliver mode volumes of <50 nm(3). Here we show that high-order plasmonic modes within additional micrometer-scale resonators surrounding each nanocavity can boost light localization to inten...

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Detalles Bibliográficos
Autores: Xomalis, Angelos, Zheng, Xuezhi, Demetriadou, Angela, Chikkaraddy, Rohit, Baumberg, Jeremy J., Martínez, Alejandro|||0000-0001-5448-0140
Tipo de recurso: artículo
Fecha de publicación:2021
País:España
Institución:Universitat Politècnica de València (UPV)
Repositorio:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
Idioma:inglés
OAI Identifier:oai:riunet.upv.es:10251/186211
Acceso en línea:https://riunet.upv.es/handle/10251/186211
Access Level:acceso abierto
Palabra clave:Nanocavity
Field enhancement
Near-field
SERS
Nano-optics
Plasmon interference
Remote excitation
TEORIA DE LA SEÑAL Y COMUNICACIONES
Descripción
Sumario:[EN] Plasmonic self-assembled nanocavities are ideal platforms for extreme light localization as they deliver mode volumes of <50 nm(3). Here we show that high-order plasmonic modes within additional micrometer-scale resonators surrounding each nanocavity can boost light localization to intensity enhancements >10(5). Plasmon interference in these hybrid microresonator nanocavities produces surface-enhanced Raman scattering (SERS) signals many-fold larger than in the bare plasmonic constructs. These now allow remote access to molecules inside the ultrathin gaps, avoiding direct irradiation and thus preventing molecular damage. Combining subnanometer gaps with micrometer-scale resonators places a high computational demand on simulations, so a generalized boundary element method (BEM) solver is developed which requires 100-fold less computational resources to characterize these systems. Our results on extreme near-field enhancement open new potential for single- molecule photonic circuits, mid-infrared detectors, and remote spectroscopy.