M-Carboranylphosphinate as Versatile Building Blocks to Design all Inorganic Coordination Polymers

The first examples of coordination polymers of manganese(II) and a nickel(II) complex with a purely inorganic carboranylphosphinate ligand are reported, together with its exhaustive characterization. X-ray analysis revealed 1D polymeric chains with carboranylphosphinate ligands bridging two manganes...

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Detalles Bibliográficos
Autores: Oleshkevich, Elena, Viñas Teixidor, Clara, Romero García, Isabel, Choquesillo Lazarte, Duane, Haukka, Matti, Teixidor Bombardó, Francesc
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2017
País:España
Institución:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Repositorio:Recercat. Dipósit de la Recerca de Catalunya
OAI Identifier:oai:recercat.cat:10256/14264
Acceso en línea:http://hdl.handle.net/10256/14264
Access Level:acceso embargado
Palabra clave:Manganès -- Compostos
Manganese compounds
Química inorgànica
Chemistry, Inorganic
Descripción
Sumario:The first examples of coordination polymers of manganese(II) and a nickel(II) complex with a purely inorganic carboranylphosphinate ligand are reported, together with its exhaustive characterization. X-ray analysis revealed 1D polymeric chains with carboranylphosphinate ligands bridging two manganese(II) centers. The reactivity of polymer 1 with water and Lewis bases has also been studied