Comparison of electron injection and recombination on TiO2 nanoparticles and ZnO nanorods photosensitized by phthalocyanine
Titanium dioxide (TiO2) and zinc oxide (ZnO) semiconductors have similar band gap positions but TiO2performs better as an anode material in dye-sensitized solar cell applications. We compared two electrodes made of TiO2nanoparticles and ZnO nanorods sensitized by an aggregation-protected phthalocyan...
| Authors: | , , , , |
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| Format: | article |
| Publication Date: | 2018 |
| Country: | España |
| Institution: | Universidad Autónoma de Madrid |
| Repository: | Biblos-e Archivo. Repositorio Institucional de la UAM |
| Language: | English |
| OAI Identifier: | oai:repositorio.uam.es:10486/686679 |
| Online Access: | http://hdl.handle.net/10486/686679 https://dx.doi.org/10.1098/rsos.180323 |
| Access Level: | Open access |
| Keyword: | Photo-induced electron transfer Phthalocyanine Semiconductor–organic interface TiO nanoparticles 2 ZnO nanorods Química |
| Summary: | Titanium dioxide (TiO2) and zinc oxide (ZnO) semiconductors have similar band gap positions but TiO2performs better as an anode material in dye-sensitized solar cell applications. We compared two electrodes made of TiO2nanoparticles and ZnO nanorods sensitized by an aggregation-protected phthalocyanine derivative using ultrafast transient absorption spectroscopy. In agreement with previous studies, the primary electron injection is two times faster on TiO2, but contrary to the previous results the charge recombination is slower on ZnO. The latter could be due to morphology differences and the ability of the injected electrons to travel much further from the sensitizer cation in ZnO nanorods |
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