Sediments as Sentinels of Pollution Episodes in the Middle Estuary of the Tinto River (SW Spain)

Estuaries are excellent environments for identifying pollution episodes that have affected river basins, as their sediments are the final destination of some of the pollutants. This paper studies the geochemical evolution of five elements (As, Co, Cu, Pb, Zn) in a core extracted from the middle estu...

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Detalles Bibliográficos
Autores: Cáceres Puro, Luis Miguel, Ruiz Muñoz, Francisco, Bermejo Meléndez, Javier, Fernández Sutilo, Lucía, González-Regalado Montero, María Luz, Rodríguez Vidal, Joaquín, Abad de los Santos, Manuel, Izquierdo, Tatiana, Toscano Grande, Antonio, Gómez Gutiérrez, Paula, Romero Aguilar, Verónica
Tipo de recurso: artículo
Fecha de publicación:2023
País:España
Institución:Universidad de Huelva (UHU)
Repositorio:Arias Montano. Repositorio Institucional de la Universidad de Huelva
Idioma:inglés
OAI Identifier:oai:ariasmontano.uhu.es:10272/22702
Acceso en línea:https://hdl.handle.net/10272/22702
Access Level:acceso abierto
Palabra clave:Sediment
Pollution
Core
Geoaccumulation index
Estuary
SW Spain
25 Ciencias de la Tierra y del Espacio
Descripción
Sumario:Estuaries are excellent environments for identifying pollution episodes that have affected river basins, as their sediments are the final destination of some of the pollutants. This paper studies the geochemical evolution of five elements (As, Co, Cu, Pb, Zn) in a core extracted from the middle estuary of the Tinto River (SW Spain). The results are based on facies interpretation, ICP atomic emission spectrometry analysis, the application of a regional background to obtain the geoaccumulation index and dating. The main objective of this communication is the detection of natural or anthropogenic pollution episodes in the middle estuary of the Tinto River (SW Spain). Four pollution episodes have been detected: (1) ~5.8 cal. kyr BP, probably caused by natural acid rock drainage processes derived from the oxidation of the Iberian Pyritic Belt deposits found in its drainage basin; (2) 4.7–4.5 kyr BP, coming from the first mining activities and characterized by a significant increase in the concentrations of the five elements analyzed; (3) 1850–1960 interval, coinciding with intensive mining and characterized by increasing values of As and, to a lesser extent, Pb (intensive mining); and (4) the second half of the 20th century, with high element concentrations from mining and industrial effluents. All episodes show an increase in their geochemical classes deduced from the geoaccumulation index. This communication can serve as an example for assessing the impact of different types of pollution in estuarine environments.