Conductive properties of triphenylene MOFs and COFs

Triphenylene (TP) based materials have experienced a great expansion in the latest years. TP molecules have interesting optoelectronic properties, arising from the aromatic core, which have been exploited in functional two-dimensional (2D) Metal-Organic Frameworks (MOFs) and Covalent Organic Framewo...

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Detalles Bibliográficos
Autores: Contreras-Pereda, Noemí, Pané, Salvador, Puigmartí Luis, Josep, Ruiz Molina, Daniel
Tipo de recurso: artículo
Fecha de publicación:2022
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/271043
Acceso en línea:http://hdl.handle.net/10261/271043
Access Level:acceso abierto
Palabra clave:Triphenylene
MOF
COF
Two-dimensional
Electronic
Functional device
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spelling Conductive properties of triphenylene MOFs and COFsContreras-Pereda, NoemíPané, SalvadorPuigmartí Luis, JosepRuiz Molina, DanielTriphenyleneMOFCOFTwo-dimensionalElectronicFunctional deviceTriphenylene (TP) based materials have experienced a great expansion in the latest years. TP molecules have interesting optoelectronic properties, arising from the aromatic core, which have been exploited in functional two-dimensional (2D) Metal-Organic Frameworks (MOFs) and Covalent Organic Frameworks (COFs) aside other organic polymers. In this review we summarize synthetic approaches of TP-based 2D MOFs and COFs emphasizing on the resulting morphology, crystalline domains and orientation, proven to have great impact on the properties and performance of these materials in functional devices. Specifically, we report a detailed description on the different TP-based 2D structures detailing the influence of the chemical and crystalline structure on the electronic properties, specially the in-plane and out-of-plane contribution to the electrical conductivity. Finally, we give also attention and present several examples of functional devices made out with these electronic materials with great impact in the literature as well as in future technological applications.This work was supported by grant RTI2018-098027-B-C21 from the Spanish Government funds and by the European Regional Development Fund (ERDF). The ICN2 is funded by the CERCA programme / Generalitat de Catalunya. The ICN2 is supported by the Severo Ochoa Centres of Excellence programme, funded by the Spanish Research Agency (AEI, grant no. SEV-2017-0706). N. C.-P. acknowledges the support of fellowship from “laCaixa” Foundation (ID 100010434). The fellowship code is LCF/BQ/ES17/11600012. J. P.-L. acknowledges support from the European Research Council Starting Grant microCrysFact (ERC-2015-STG No. 677020), the Swiss National Science Foundation (project no. 200021_181988), and grant PID2020-116612RB-C33 funded by MCIN/ AEI /10.13039/501100011033. S.P. acknowledges support from the ERC-2017-CoG HINBOTS Grant No. 771565.ElsevierEuropean CommissionGeneralitat de CatalunyaAgencia Estatal de Investigación (España)La CaixaSwiss National Science FoundationMinisterio de Ciencia, Innovación y Universidades (España)Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]2022202220222022info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_dcae04bchttp://hdl.handle.net/10261/271043reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Inglés#PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE#info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-098027-B-C21info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2020-116612RB-C33http://doi.org/10.1016/j.ccr.2022.214459Síinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/2710432026-05-22T06:33:51Z
dc.title.none.fl_str_mv Conductive properties of triphenylene MOFs and COFs
title Conductive properties of triphenylene MOFs and COFs
spellingShingle Conductive properties of triphenylene MOFs and COFs
Contreras-Pereda, Noemí
Triphenylene
MOF
COF
Two-dimensional
Electronic
Functional device
title_short Conductive properties of triphenylene MOFs and COFs
title_full Conductive properties of triphenylene MOFs and COFs
title_fullStr Conductive properties of triphenylene MOFs and COFs
title_full_unstemmed Conductive properties of triphenylene MOFs and COFs
title_sort Conductive properties of triphenylene MOFs and COFs
dc.creator.none.fl_str_mv Contreras-Pereda, Noemí
Pané, Salvador
Puigmartí Luis, Josep
Ruiz Molina, Daniel
author Contreras-Pereda, Noemí
author_facet Contreras-Pereda, Noemí
Pané, Salvador
Puigmartí Luis, Josep
Ruiz Molina, Daniel
author_role author
author2 Pané, Salvador
Puigmartí Luis, Josep
Ruiz Molina, Daniel
author2_role author
author
author
dc.contributor.none.fl_str_mv European Commission
Generalitat de Catalunya
Agencia Estatal de Investigación (España)
La Caixa
Swiss National Science Foundation
Ministerio de Ciencia, Innovación y Universidades (España)
Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]
dc.subject.none.fl_str_mv Triphenylene
MOF
COF
Two-dimensional
Electronic
Functional device
topic Triphenylene
MOF
COF
Two-dimensional
Electronic
Functional device
description Triphenylene (TP) based materials have experienced a great expansion in the latest years. TP molecules have interesting optoelectronic properties, arising from the aromatic core, which have been exploited in functional two-dimensional (2D) Metal-Organic Frameworks (MOFs) and Covalent Organic Frameworks (COFs) aside other organic polymers. In this review we summarize synthetic approaches of TP-based 2D MOFs and COFs emphasizing on the resulting morphology, crystalline domains and orientation, proven to have great impact on the properties and performance of these materials in functional devices. Specifically, we report a detailed description on the different TP-based 2D structures detailing the influence of the chemical and crystalline structure on the electronic properties, specially the in-plane and out-of-plane contribution to the electrical conductivity. Finally, we give also attention and present several examples of functional devices made out with these electronic materials with great impact in the literature as well as in future technological applications.
publishDate 2022
dc.date.none.fl_str_mv 2022
2022
2022
2022
dc.type.none.fl_str_mv info:eu-repo/semantics/article
http://purl.org/coar/resource_type/c_dcae04bc
format article
dc.identifier.none.fl_str_mv http://hdl.handle.net/10261/271043
url http://hdl.handle.net/10261/271043
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv #PLACEHOLDER_PARENT_METADATA_VALUE#
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info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-098027-B-C21
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2020-116612RB-C33
http://doi.org/10.1016/j.ccr.2022.214459
Sí
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC
instname:Consejo Superior de Investigaciones Científicas (CSIC)
instname_str Consejo Superior de Investigaciones Científicas (CSIC)
reponame_str DIGITAL.CSIC. Repositorio Institucional del CSIC
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