Development of chiral methodologies by Capillary Electrophoresis with ultraviolet and Mass Spectrometry detection for duloxetine analysis in pharmaceutical formulations

Two chiral methodologies were developed by capillary electrophoresis (CE) with UV and mass spectrometry (MS) detection to ensure the quality control of the drug duloxetine, commercialized as a pure enantiomer. Both methods were optimized to achieve a high baseline enantioresolution (Rs > 2) and a...

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Bibliographic Details
Authors: Sánchez López, Elena, Montealegre Dondarza, Cristina, Marina Alegre, María Luisa|||0000-0002-5583-1624, Crego Navazo, Antonio Luis|||0000-0002-4083-5294
Format: article
Publication Date:2014
Country:España
Institution:Universidad de Alcalá (UAH)
Repository:e_Buah Biblioteca Digital Universidad de Alcalá
Language:English
OAI Identifier:oai:ebuah.uah.es:10017/49007
Online Access:http://hdl.handle.net/10017/49007
https://dx.doi.org/10.1016/j.chroma.2014.07.038
Access Level:Open access
Keyword:Capillary electrophoresis
Duloxetine
Enantioseparation
Mass spectrometry
Partial filling technique
Química
Chemistry
Description
Summary:Two chiral methodologies were developed by capillary electrophoresis (CE) with UV and mass spectrometry (MS) detection to ensure the quality control of the drug duloxetine, commercialized as a pure enantiomer. Both methods were optimized to achieve a high baseline enantioresolution (Rs > 2) and an acceptable precision (RSD values 0.05). (C) 2014 Elsevier B.V. All rights reserved.