Multifunctional Lanthanide-Based Metal-Organic Frameworks Derived from 3-Amino-4-hydroxybenzoate: Single-Molecule Magnet Behavior, Luminescent Properties for Thermometry, and CO2 Adsorptive Capacity

Herein, we describe and study a new family of isostructural multifunctional metal-organic frameworks (MOFs) with the formula {[Ln(5)L(6)(OH)(3)(DMF)(3)]center dot 5H(2)O} n (where (H2L) is 3-amino-4-hydroxybenzoic acid ligand) for magnetism and photoluminescence. Interestingly, three of the material...

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Autores: Echenique Errandonea, Estitxu, Mendes, Ricardo F., Figueira, Flavio, Choquesillo Lazarte, Duane, Beobide Pacheco, Garikoitz, Cepeda Ruiz, Javier, Ananias, Duarte, Rodríguez Diéguez, Antonio, Almeida Paz, Filipe A., Seco Botana, José Manuel
Tipo de recurso: artículo
Fecha de publicación:2022
País:España
Institución:Universidad del País Vasco
Repositorio:Addi. Archivo Digital para la Docencia y la Investigación
OAI Identifier:oai:addi.ehu.eus:10810/58244
Acceso en línea:http://hdl.handle.net/10810/58244
Access Level:acceso abierto
Palabra clave:crystal structures
gas adsorption
coordination polymers
ralaxation
ytterbium
capture
phosphonate
separation
design
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spelling Multifunctional Lanthanide-Based Metal-Organic Frameworks Derived from 3-Amino-4-hydroxybenzoate: Single-Molecule Magnet Behavior, Luminescent Properties for Thermometry, and CO2 Adsorptive CapacityEchenique Errandonea, EstitxuMendes, Ricardo F.Figueira, FlavioChoquesillo Lazarte, DuaneBeobide Pacheco, GarikoitzCepeda Ruiz, JavierAnanias, DuarteRodríguez Diéguez, AntonioAlmeida Paz, Filipe A.Seco Botana, José Manuelcrystal structuresgas adsorptioncoordination polymersralaxationytterbiumcapturephosphonateseparationdesignHerein, we describe and study a new family of isostructural multifunctional metal-organic frameworks (MOFs) with the formula {[Ln(5)L(6)(OH)(3)(DMF)(3)]center dot 5H(2)O} n (where (H2L) is 3-amino-4-hydroxybenzoic acid ligand) for magnetism and photoluminescence. Interestingly, three of the materials (Dy-, Er-, and Yb-based MOFs) present singlemolecule magnet (SMM) behavior derived from the magnetic anisotropy of the lanthanide ions as a consequence of the adequate electronic distribution of the coordination environment. Additionally, photoluminescence properties of the ligand in combination with Eu and Tb counterparts were studied, including the heterometallic Eu-Tb mixed MOF that shows potential as ratiometric luminescent thermometers. Finally, the porous nature of the framework allowed showing the CO2 sorption capacity.E.E. is grateful to the Government of the Basque Country for the predoctoral fellowship and R.F.M. to the Junior Research Position CEECIND/ 00553/2017. The research contract of FF (REF-168-89-ARH/2018) is funded by national funds (OE), through FCT, in the scope of the framework contract foreseen in nos. 4, 5, and 6 of article 23 of the Decree-Law 57/2016, of 29 August, changed by Law 57/2017, of 19 July. This work was developed within the scope of the projects given by the Spanish Ministry of Science, Innovation and Universities (MCIU/AEI/ FEDER, UE) (PGC2018-102052-A-C22, PGC2018-102052-BC21, and PID2019-108028GB-C21), Gobierno Vasco/Eusko Jaurlaritza (IT1310-19 and IT1291-19), Junta de Andalucia (FQM-394), University of the Basque Country (GIU 20/028), and CICECO-Aveiro Institute of Materials (UIDB/50011/ 2020 and UIDP/50011/2020).American Chemical Society202220222022info:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10810/58244reponame:Addi. Archivo Digital para la Docencia y la Investigacióninstname:Universidad del País VascoInglésinfo:eu-repo/grantAgreement/MICIU/PGC2018-102052-A-C22/info:eu-repo/grantAgreement/MICIU/PGC2018-102052-B-C21/info:eu-repo/grantAgreement/MICINN/PID2019-108028GB-C21/https://pubs.acs.org/doi/10.1021/acs.inorgchem.2c00544info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by/3.0/es/© 2022 The Authors. Published by American Chemical Society under a Creative Commons license Attribution 4.0 International (CC BY 4.0)Atribución 3.0 Españaoai:addi.ehu.eus:10810/582442026-06-18T09:23:17Z
dc.title.none.fl_str_mv Multifunctional Lanthanide-Based Metal-Organic Frameworks Derived from 3-Amino-4-hydroxybenzoate: Single-Molecule Magnet Behavior, Luminescent Properties for Thermometry, and CO2 Adsorptive Capacity
title Multifunctional Lanthanide-Based Metal-Organic Frameworks Derived from 3-Amino-4-hydroxybenzoate: Single-Molecule Magnet Behavior, Luminescent Properties for Thermometry, and CO2 Adsorptive Capacity
spellingShingle Multifunctional Lanthanide-Based Metal-Organic Frameworks Derived from 3-Amino-4-hydroxybenzoate: Single-Molecule Magnet Behavior, Luminescent Properties for Thermometry, and CO2 Adsorptive Capacity
Echenique Errandonea, Estitxu
crystal structures
gas adsorption
coordination polymers
ralaxation
ytterbium
capture
phosphonate
separation
design
title_short Multifunctional Lanthanide-Based Metal-Organic Frameworks Derived from 3-Amino-4-hydroxybenzoate: Single-Molecule Magnet Behavior, Luminescent Properties for Thermometry, and CO2 Adsorptive Capacity
title_full Multifunctional Lanthanide-Based Metal-Organic Frameworks Derived from 3-Amino-4-hydroxybenzoate: Single-Molecule Magnet Behavior, Luminescent Properties for Thermometry, and CO2 Adsorptive Capacity
title_fullStr Multifunctional Lanthanide-Based Metal-Organic Frameworks Derived from 3-Amino-4-hydroxybenzoate: Single-Molecule Magnet Behavior, Luminescent Properties for Thermometry, and CO2 Adsorptive Capacity
title_full_unstemmed Multifunctional Lanthanide-Based Metal-Organic Frameworks Derived from 3-Amino-4-hydroxybenzoate: Single-Molecule Magnet Behavior, Luminescent Properties for Thermometry, and CO2 Adsorptive Capacity
title_sort Multifunctional Lanthanide-Based Metal-Organic Frameworks Derived from 3-Amino-4-hydroxybenzoate: Single-Molecule Magnet Behavior, Luminescent Properties for Thermometry, and CO2 Adsorptive Capacity
dc.creator.none.fl_str_mv Echenique Errandonea, Estitxu
Mendes, Ricardo F.
Figueira, Flavio
Choquesillo Lazarte, Duane
Beobide Pacheco, Garikoitz
Cepeda Ruiz, Javier
Ananias, Duarte
Rodríguez Diéguez, Antonio
Almeida Paz, Filipe A.
Seco Botana, José Manuel
author Echenique Errandonea, Estitxu
author_facet Echenique Errandonea, Estitxu
Mendes, Ricardo F.
Figueira, Flavio
Choquesillo Lazarte, Duane
Beobide Pacheco, Garikoitz
Cepeda Ruiz, Javier
Ananias, Duarte
Rodríguez Diéguez, Antonio
Almeida Paz, Filipe A.
Seco Botana, José Manuel
author_role author
author2 Mendes, Ricardo F.
Figueira, Flavio
Choquesillo Lazarte, Duane
Beobide Pacheco, Garikoitz
Cepeda Ruiz, Javier
Ananias, Duarte
Rodríguez Diéguez, Antonio
Almeida Paz, Filipe A.
Seco Botana, José Manuel
author2_role author
author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv crystal structures
gas adsorption
coordination polymers
ralaxation
ytterbium
capture
phosphonate
separation
design
topic crystal structures
gas adsorption
coordination polymers
ralaxation
ytterbium
capture
phosphonate
separation
design
description Herein, we describe and study a new family of isostructural multifunctional metal-organic frameworks (MOFs) with the formula {[Ln(5)L(6)(OH)(3)(DMF)(3)]center dot 5H(2)O} n (where (H2L) is 3-amino-4-hydroxybenzoic acid ligand) for magnetism and photoluminescence. Interestingly, three of the materials (Dy-, Er-, and Yb-based MOFs) present singlemolecule magnet (SMM) behavior derived from the magnetic anisotropy of the lanthanide ions as a consequence of the adequate electronic distribution of the coordination environment. Additionally, photoluminescence properties of the ligand in combination with Eu and Tb counterparts were studied, including the heterometallic Eu-Tb mixed MOF that shows potential as ratiometric luminescent thermometers. Finally, the porous nature of the framework allowed showing the CO2 sorption capacity.
publishDate 2022
dc.date.none.fl_str_mv 2022
2022
2022
dc.type.none.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv http://hdl.handle.net/10810/58244
url http://hdl.handle.net/10810/58244
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv info:eu-repo/grantAgreement/MICIU/PGC2018-102052-A-C22/
info:eu-repo/grantAgreement/MICIU/PGC2018-102052-B-C21/
info:eu-repo/grantAgreement/MICINN/PID2019-108028GB-C21/
https://pubs.acs.org/doi/10.1021/acs.inorgchem.2c00544
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by/3.0/es/
Atribución 3.0 España
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by/3.0/es/
Atribución 3.0 España
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:Addi. Archivo Digital para la Docencia y la Investigación
instname:Universidad del País Vasco
instname_str Universidad del País Vasco
reponame_str Addi. Archivo Digital para la Docencia y la Investigación
collection Addi. Archivo Digital para la Docencia y la Investigación
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,300719

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