Resistance of class C fly ash belite cement to simulated sodium sulphate radioactive liquid waste attack
5 pages.-- Final full-text version of the paper available at: http://dx.doi.org/10.1016/j.jhazmat.2008.04.086.
| Autores: | , , |
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| Formato: | artículo |
| Fecha de publicación: | 2008 |
| País: | España |
| Recursos: | Consejo Superior de Investigaciones Científicas (CSIC) |
| Repositorio: | DIGITAL.CSIC. Repositorio Institucional del CSIC |
| OAI Identifier: | oai:digital.csic.es:10261/4956 |
| Acesso em linha: | http://hdl.handle.net/10261/4956 |
| Access Level: | acceso abierto |
| Palavra-chave: | Fly-ash belite cement Durability Sulphate waste Microstructure |
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Resistance of class C fly ash belite cement to simulated sodium sulphate radioactive liquid waste attackGuerrero Bustos, Ana MaríaGoñi Elizalde, SaraRodríguez Allegro, VirginiaFly-ash belite cementDurabilitySulphate wasteMicrostructure5 pages.-- Final full-text version of the paper available at: http://dx.doi.org/10.1016/j.jhazmat.2008.04.086.The resistance of class C fly ash belite cement (FABC-2-W)to concentrated sodium sulphate salts associated with low level wastes (LLW) and medium level wastes (MLW) is discussed. This study was carried out according to the Koch and Steinegger methodology by testing the flexural strength of mortars immersed in simulated radioactive liquid waste rich in sulphate (48 000 ppm) and demineralised water (used as a reference), at 20ºC and 40ºC over a period of 180 days. The reaction mechanisms of sulphate ion with the mortar was carried out through a microstructure study, which included the use of Scanning electron microscopy (SEM), porosity and pore-size distribution and X-ray diffraction (XRD). The results showed that the FABC mortar was stable against simulated sulphate radioactive liquid waste (SSRLW) attack at the two chosen temperatures. The enhancement of mechanical properties was a result of the formation of non-expansive ettringite inside the pores and an alkaline activation of the hydraulic activity of cement promoted by the ingress of sulphate. Accordingly, the microstructure was strongly refined.Funding for the present research was provided by the Minister of Science and Technology under Project n◦ MAT 2002-04023-CO3. The authors wish to thank the Thermal Station of Cercs (Catalonia) for the fly ash supplied.Peer reviewedElsevierConsejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]200820082008info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501927806 bytesapplication/pdfhttp://hdl.handle.net/10261/4956http://dx.doi.org/10.1016/j.jhazmat.2008.04.086reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)InglésSíinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/49562026-05-22T06:33:51Z |
| dc.title.none.fl_str_mv |
Resistance of class C fly ash belite cement to simulated sodium sulphate radioactive liquid waste attack |
| title |
Resistance of class C fly ash belite cement to simulated sodium sulphate radioactive liquid waste attack |
| spellingShingle |
Resistance of class C fly ash belite cement to simulated sodium sulphate radioactive liquid waste attack Guerrero Bustos, Ana María Fly-ash belite cement Durability Sulphate waste Microstructure |
| title_short |
Resistance of class C fly ash belite cement to simulated sodium sulphate radioactive liquid waste attack |
| title_full |
Resistance of class C fly ash belite cement to simulated sodium sulphate radioactive liquid waste attack |
| title_fullStr |
Resistance of class C fly ash belite cement to simulated sodium sulphate radioactive liquid waste attack |
| title_full_unstemmed |
Resistance of class C fly ash belite cement to simulated sodium sulphate radioactive liquid waste attack |
| title_sort |
Resistance of class C fly ash belite cement to simulated sodium sulphate radioactive liquid waste attack |
| dc.creator.none.fl_str_mv |
Guerrero Bustos, Ana María Goñi Elizalde, Sara Rodríguez Allegro, Virginia |
| author |
Guerrero Bustos, Ana María |
| author_facet |
Guerrero Bustos, Ana María Goñi Elizalde, Sara Rodríguez Allegro, Virginia |
| author_role |
author |
| author2 |
Goñi Elizalde, Sara Rodríguez Allegro, Virginia |
| author2_role |
author author |
| dc.contributor.none.fl_str_mv |
Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72] |
| dc.subject.none.fl_str_mv |
Fly-ash belite cement Durability Sulphate waste Microstructure |
| topic |
Fly-ash belite cement Durability Sulphate waste Microstructure |
| description |
5 pages.-- Final full-text version of the paper available at: http://dx.doi.org/10.1016/j.jhazmat.2008.04.086. |
| publishDate |
2008 |
| dc.date.none.fl_str_mv |
2008 2008 2008 |
| dc.type.none.fl_str_mv |
info:eu-repo/semantics/article http://purl.org/coar/resource_type/c_6501 |
| format |
article |
| dc.identifier.none.fl_str_mv |
http://hdl.handle.net/10261/4956 |
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http://hdl.handle.net/10261/4956 |
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Inglés |
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Inglés |
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Sí |
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info:eu-repo/semantics/openAccess |
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openAccess |
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927806 bytes application/pdf |
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Elsevier |
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Elsevier |
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http://dx.doi.org/10.1016/j.jhazmat.2008.04.086 reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC instname:Consejo Superior de Investigaciones Científicas (CSIC) |
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Consejo Superior de Investigaciones Científicas (CSIC) |
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DIGITAL.CSIC. Repositorio Institucional del CSIC |
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DIGITAL.CSIC. Repositorio Institucional del CSIC |
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1869408622801321984 |
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15,812429 |