Sulfur-doped carbon nanofibers as support for tantalum oxides bifunctional catalysts for the oxygen reduction and evolution reactions

10 figures, 7 tables.-- Supplementary information available.

Detalles Bibliográficos
Autores: Ruiz Cornejo, Juan Carlos, Sebastián del Río, David, Pardo, Juan Ignacio, Martínez Huerta, M. Victoria, Lázaro Elorri, María Jesús
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2022
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/278524
Acceso en línea:http://hdl.handle.net/10261/278524
Access Level:acceso abierto
Palabra clave:Sulfur-doped carbon nanofibers
Tantalum oxide
Bifunctional electrocatalyst
Oxygen evolution reaction
Oxygen reduction reaction
http://metadata.un.org/sdg/7
Ensure access to affordable, reliable, sustainable and modern energy for all
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spelling Sulfur-doped carbon nanofibers as support for tantalum oxides bifunctional catalysts for the oxygen reduction and evolution reactionsRuiz Cornejo, Juan CarlosSebastián del Río, DavidPardo, Juan IgnacioMartínez Huerta, M. VictoriaLázaro Elorri, María JesúsSulfur-doped carbon nanofibersTantalum oxideBifunctional electrocatalystOxygen evolution reactionOxygen reduction reactionhttp://metadata.un.org/sdg/7Ensure access to affordable, reliable, sustainable and modern energy for all10 figures, 7 tables.-- Supplementary information available.Highly efficient, low-cost and stable bifunctional catalysts for oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) are highly desirable for the development of green electrochemical energy storage and conversion devices. Here, we report the synthesis of sulfur-doped carbon nanofibers (CNF) as support for tantalum oxide nanoparticles. Carbon nanofibers and tantalum oxides represent a durable choice for oxygen electrocatalysis, but an improvement of catalytic activity is required. Upon doping, sulfur is found to be mainly bonded to carbon as C–S–C species (more than 80%). The results show that the effective incorporation of sulfur in the support has a clear positive effect on the electroactivity of the tantalum oxide catalysts. It causes a decrease of OER/ORR overpotential of 80 mV with respect to the undoped counterpart, with special improvement in the ORR. The new catalysts have shown an interesting bifunctional behavior for the OER and ORR, as well as a good stability through time.The authors wish to acknowledge the grants PID2020-115848RB-C21 and PID2020-115848RB-C22 funded by MCIN/AEI/10.13039/501100011033, and to the Gobierno de Aragón (DGA) for the funding to Grupo de Conversión de Combustibles (T06_17R). J.C. Ruiz-Cornejo acknowledges also DGA for his PhD grant.Peer reviewedElsevier BVMinisterio de Ciencia e Innovación (España)Agencia Estatal de Investigación (España)Gobierno de AragónEuropean CommissionSebastián del Río, David [0000-0002-7722-2993]Martínez Huerta, M.ª Victoria [0000-0002-2644-0982]Lázaro Elorri, María Jesús [0000-0002-4769-2564]Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]202220222022info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Publisher's versioninfo:eu-repo/semantics/publishedVersionhttp://hdl.handle.net/10261/278524reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Inglés#PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE#info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2020-115848RB-C21info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2020-115848RB-C22info:eu-repo/grantAgreement/DGA//T06_17Rhttp://dx.doi.org/10.1016/j.jpowsour.2022.231988Síinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/2785242026-05-22T06:33:51Z
dc.title.none.fl_str_mv Sulfur-doped carbon nanofibers as support for tantalum oxides bifunctional catalysts for the oxygen reduction and evolution reactions
title Sulfur-doped carbon nanofibers as support for tantalum oxides bifunctional catalysts for the oxygen reduction and evolution reactions
spellingShingle Sulfur-doped carbon nanofibers as support for tantalum oxides bifunctional catalysts for the oxygen reduction and evolution reactions
Ruiz Cornejo, Juan Carlos
Sulfur-doped carbon nanofibers
Tantalum oxide
Bifunctional electrocatalyst
Oxygen evolution reaction
Oxygen reduction reaction
http://metadata.un.org/sdg/7
Ensure access to affordable, reliable, sustainable and modern energy for all
title_short Sulfur-doped carbon nanofibers as support for tantalum oxides bifunctional catalysts for the oxygen reduction and evolution reactions
title_full Sulfur-doped carbon nanofibers as support for tantalum oxides bifunctional catalysts for the oxygen reduction and evolution reactions
title_fullStr Sulfur-doped carbon nanofibers as support for tantalum oxides bifunctional catalysts for the oxygen reduction and evolution reactions
title_full_unstemmed Sulfur-doped carbon nanofibers as support for tantalum oxides bifunctional catalysts for the oxygen reduction and evolution reactions
title_sort Sulfur-doped carbon nanofibers as support for tantalum oxides bifunctional catalysts for the oxygen reduction and evolution reactions
dc.creator.none.fl_str_mv Ruiz Cornejo, Juan Carlos
Sebastián del Río, David
Pardo, Juan Ignacio
Martínez Huerta, M. Victoria
Lázaro Elorri, María Jesús
author Ruiz Cornejo, Juan Carlos
author_facet Ruiz Cornejo, Juan Carlos
Sebastián del Río, David
Pardo, Juan Ignacio
Martínez Huerta, M. Victoria
Lázaro Elorri, María Jesús
author_role author
author2 Sebastián del Río, David
Pardo, Juan Ignacio
Martínez Huerta, M. Victoria
Lázaro Elorri, María Jesús
author2_role author
author
author
author
dc.contributor.none.fl_str_mv Ministerio de Ciencia e Innovación (España)
Agencia Estatal de Investigación (España)
Gobierno de Aragón
European Commission
Sebastián del Río, David [0000-0002-7722-2993]
Martínez Huerta, M.ª Victoria [0000-0002-2644-0982]
Lázaro Elorri, María Jesús [0000-0002-4769-2564]
Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]
dc.subject.none.fl_str_mv Sulfur-doped carbon nanofibers
Tantalum oxide
Bifunctional electrocatalyst
Oxygen evolution reaction
Oxygen reduction reaction
http://metadata.un.org/sdg/7
Ensure access to affordable, reliable, sustainable and modern energy for all
topic Sulfur-doped carbon nanofibers
Tantalum oxide
Bifunctional electrocatalyst
Oxygen evolution reaction
Oxygen reduction reaction
http://metadata.un.org/sdg/7
Ensure access to affordable, reliable, sustainable and modern energy for all
description 10 figures, 7 tables.-- Supplementary information available.
publishDate 2022
dc.date.none.fl_str_mv 2022
2022
2022
dc.type.none.fl_str_mv info:eu-repo/semantics/article
http://purl.org/coar/resource_type/c_6501
Publisher's version
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10261/278524
url http://hdl.handle.net/10261/278524
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv #PLACEHOLDER_PARENT_METADATA_VALUE#
#PLACEHOLDER_PARENT_METADATA_VALUE#
#PLACEHOLDER_PARENT_METADATA_VALUE#
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2020-115848RB-C21
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2020-115848RB-C22
info:eu-repo/grantAgreement/DGA//T06_17R
http://dx.doi.org/10.1016/j.jpowsour.2022.231988
Sí
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv Elsevier BV
publisher.none.fl_str_mv Elsevier BV
dc.source.none.fl_str_mv reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC
instname:Consejo Superior de Investigaciones Científicas (CSIC)
instname_str Consejo Superior de Investigaciones Científicas (CSIC)
reponame_str DIGITAL.CSIC. Repositorio Institucional del CSIC
collection DIGITAL.CSIC. Repositorio Institucional del CSIC
repository.name.fl_str_mv
repository.mail.fl_str_mv
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