Synthesis and structure of complexes of acyl N-aminides with zinc(II) salts

The structures of complexes obtained by reacting acyl N-aminides and ZnCl2 were ascertained by X-ray analysis and were show to incorporate one Zn atom and two molecules of the N-aminide in a distorted tetrahedral geometry. Bis-aminides act as bidentate ligands forming ZnLCl2 complexes.

Bibliographic Details
Authors: Molina Ponce, Andrés, Heras Muñoz, María Amor de las, Martínez del Amo, Yolanda, Vaquero López, Juan José|||0000-0002-3820-9673, García Navío, José Luis, Álvarez-Builla Gómez, Julio, Gómez Sal, Pilar|||0000-0002-9279-210X, Torres, Rosario
Format: article
Publication Date:1997
Country:España
Institution:Universidad de Alcalá (UAH)
Repository:e_Buah Biblioteca Digital Universidad de Alcalá
Language:English
OAI Identifier:oai:ebuah.uah.es:10017/4175
Online Access:http://hdl.handle.net/10017/4175
https://dx.doi.org/10.1016/S0040-4020(97)00300-1
Access Level:Open access
Keyword:Complexes of acyl N-aminides with zinc(II) salts
Ciencia
Química orgánica
Science
Chemistry, organic
Description
Summary:The structures of complexes obtained by reacting acyl N-aminides and ZnCl2 were ascertained by X-ray analysis and were show to incorporate one Zn atom and two molecules of the N-aminide in a distorted tetrahedral geometry. Bis-aminides act as bidentate ligands forming ZnLCl2 complexes.

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