Freezing of adhesive hard-spheres
A theoretical study of the freezing of adhesive hard spheres within the generalized-effective-liquid approximation has been performed. The liquid-solid phase diagram exhibits most of the trends observed for simple liquids. There is, however, no triple point because the solid phase becomes mechanical...
| Autores: | , |
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| Tipo de recurso: | artículo |
| Fecha de publicación: | 1993 |
| País: | España |
| Institución: | Universidad Complutense de Madrid (UCM) |
| Repositorio: | Docta Complutense |
| Idioma: | inglés |
| OAI Identifier: | oai:docta.ucm.es:20.500.14352/58889 |
| Acceso en línea: | https://hdl.handle.net/20.500.14352/58889 |
| Access Level: | acceso abierto |
| Palabra clave: | 536 Density-Functional Theory Liquid-Solid Transition Simulation Systems Model Termodinámica 2213 Termodinámica |
| Sumario: | A theoretical study of the freezing of adhesive hard spheres within the generalized-effective-liquid approximation has been performed. The liquid-solid phase diagram exhibits most of the trends observed for simple liquids. There is, however, no triple point because the solid phase becomes mechanically unstable iii the region where the liquid-solid transition crosses the percolation transition. A useful closed-form expression for the free energy of the fluid phases is also given. |
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