Heterometallic Cube-Type Molecular Nitrides

A wide family of heterometallic nitrido complexes with [MTi3N4] cube-type cores has been prepared by incorporation of most of the metallic elements of the Periodic Table into the incomplete cube structure of [{TiCp*(μ-NH)}3(μ3-N)] (Cp* = η5-C5Me5).

Bibliographic Details
Authors: Mena Montoro, Miguel|||0000-0001-7456-1212, Pérez Redondo, Adrián|||0000-0002-0086-8825, Yélamos Sánchez, Carlos|||0000-0003-0425-4799
Format: article
Publication Date:2016
Country:España
Institution:Universidad de Alcalá (UAH)
Repository:e_Buah Biblioteca Digital Universidad de Alcalá
Language:English
OAI Identifier:oai:ebuah.uah.es:10017/38287
Online Access:http://hdl.handle.net/10017/38287
https://dx.doi.org/10.1002/ejic.201600135
Access Level:Open access
Keyword:Cage compounds
Titanium
Nitrides
Heterometallic complexes
Cubanes
Química
Chemistry
Description
Summary:A wide family of heterometallic nitrido complexes with [MTi3N4] cube-type cores has been prepared by incorporation of most of the metallic elements of the Periodic Table into the incomplete cube structure of [{TiCp*(μ-NH)}3(μ3-N)] (Cp* = η5-C5Me5).