Complete transformation of aluminum waste into zeolite and its use in the removal of pollutants from aqueous solution
Mención Internacional en el título de Doctor
| Autor: | |
|---|---|
| Tipo de recurso: | tesis doctoral |
| Fecha de publicación: | 2018 |
| País: | España |
| Institución: | Consejo Superior de Investigaciones Científicas (CSIC) |
| Repositorio: | DIGITAL.CSIC. Repositorio Institucional del CSIC |
| OAI Identifier: | oai:digital.csic.es:10261/173003 |
| Acceso en línea: | http://hdl.handle.net/10261/173003 |
| Access Level: | acceso abierto |
| Palabra clave: | Heavy metals Hazardous aluminum waste Zeolites Adsorption Hydrothermal synthesis Water polution |
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Complete transformation of aluminum waste into zeolite and its use in the removal of pollutants from aqueous solutionSánchez Hernández, RuthHeavy metalsHazardous aluminum wasteZeolitesAdsorptionHydrothermal synthesisWater polutionMención Internacional en el título de DoctorZero Waste concept aims to minimize the negative effects of the generation and management of waste on human health and the environment, as well as to reduce the use of natural resources. The novelty of this Thesis comes from the development of a simple procedure to completely transform a hazardous aluminum waste into added-value materials of great industrial interest, as zeolites, which are used later as adsorbents for the removal of heavy metals and ammonium from aqueous effluents. There are not previous works related to the use of the hazardous aluminum waste as a raw material for the synthesis of zeolites. In this work the following stages were developed: i) Characterization of different aluminum wastes to get a representative sample. ii) Lab-scale hydrothermal synthesis and characterization of zeolites from aluminum waste to define the optimal experimental conditions. iii) Scaling up of the process (bench-scale synthesis) to assess its industrial application. iv) Development of a more sustainable synthesis process by alkaline effluents recycling in order to achieve a zero waste and zero effluents process. v) Using the zeolites as adsorbents for the removal of heavy metals and ammonium to decontaminate water. Aluminum waste, due to its high aluminum content (Al2O3 ~ 66 wt.%), was characterized and used as the only aluminum raw material for the lab- and bench-scale synthesis of zeolites in the Na2O-Al2O3-SiO2-H2O system. The synthesized zeolites exhibited high cation exchange capacities (CEC) and suitable adsorption properties, resulting in potential adsorbents for the removal of heavy metals and ammonium from aqueous solutions.Peer reviewedUniversidad Carlos III de MadridConsejo Superior de Investigaciones Científicas (España)López Delgado, AuroraLópez Andrés, SolConsejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]201820182018info:eu-repo/semantics/doctoralThesishttp://purl.org/coar/resource_type/c_db06http://hdl.handle.net/10261/173003reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)InglésSíinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/1730032026-05-22T06:33:51Z |
| dc.title.none.fl_str_mv |
Complete transformation of aluminum waste into zeolite and its use in the removal of pollutants from aqueous solution |
| title |
Complete transformation of aluminum waste into zeolite and its use in the removal of pollutants from aqueous solution |
| spellingShingle |
Complete transformation of aluminum waste into zeolite and its use in the removal of pollutants from aqueous solution Sánchez Hernández, Ruth Heavy metals Hazardous aluminum waste Zeolites Adsorption Hydrothermal synthesis Water polution |
| title_short |
Complete transformation of aluminum waste into zeolite and its use in the removal of pollutants from aqueous solution |
| title_full |
Complete transformation of aluminum waste into zeolite and its use in the removal of pollutants from aqueous solution |
| title_fullStr |
Complete transformation of aluminum waste into zeolite and its use in the removal of pollutants from aqueous solution |
| title_full_unstemmed |
Complete transformation of aluminum waste into zeolite and its use in the removal of pollutants from aqueous solution |
| title_sort |
Complete transformation of aluminum waste into zeolite and its use in the removal of pollutants from aqueous solution |
| dc.creator.none.fl_str_mv |
Sánchez Hernández, Ruth |
| author |
Sánchez Hernández, Ruth |
| author_facet |
Sánchez Hernández, Ruth |
| author_role |
author |
| dc.contributor.none.fl_str_mv |
López Delgado, Aurora López Andrés, Sol Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72] |
| dc.subject.none.fl_str_mv |
Heavy metals Hazardous aluminum waste Zeolites Adsorption Hydrothermal synthesis Water polution |
| topic |
Heavy metals Hazardous aluminum waste Zeolites Adsorption Hydrothermal synthesis Water polution |
| description |
Mención Internacional en el título de Doctor |
| publishDate |
2018 |
| dc.date.none.fl_str_mv |
2018 2018 2018 |
| dc.type.none.fl_str_mv |
info:eu-repo/semantics/doctoralThesis http://purl.org/coar/resource_type/c_db06 |
| format |
doctoralThesis |
| dc.identifier.none.fl_str_mv |
http://hdl.handle.net/10261/173003 |
| url |
http://hdl.handle.net/10261/173003 |
| dc.language.none.fl_str_mv |
Inglés |
| language_invalid_str_mv |
Inglés |
| dc.relation.none.fl_str_mv |
Sí |
| dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess |
| eu_rights_str_mv |
openAccess |
| dc.publisher.none.fl_str_mv |
Universidad Carlos III de Madrid Consejo Superior de Investigaciones Científicas (España) |
| publisher.none.fl_str_mv |
Universidad Carlos III de Madrid Consejo Superior de Investigaciones Científicas (España) |
| dc.source.none.fl_str_mv |
reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC instname:Consejo Superior de Investigaciones Científicas (CSIC) |
| instname_str |
Consejo Superior de Investigaciones Científicas (CSIC) |
| reponame_str |
DIGITAL.CSIC. Repositorio Institucional del CSIC |
| collection |
DIGITAL.CSIC. Repositorio Institucional del CSIC |
| repository.name.fl_str_mv |
|
| repository.mail.fl_str_mv |
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| _version_ |
1869408341866840064 |
| score |
15,811543 |