Determination of Pd(II) using an antimony film coated on a screen-printed electrode by adsorptive stripping voltammetry
The use of an antimony film coated on a screen-printed carbon electrode (ex-situ SbSPCE) is proposed for the determination of Pd(II) at ppb levels in natural samples by adsorptive stripping voltammetry using dimethylglyoxime as chelating agent. Ex-situ SbSPCE produces a better analytical performance...
| Authors: | , , , , , |
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| Format: | article |
| Status: | Versión aceptada para publicación |
| Publication Date: | 2017 |
| Country: | España |
| Institution: | Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya) |
| Repository: | Recercat. Dipósit de la Recerca de Catalunya |
| OAI Identifier: | oai:recercat.cat:2445/125567 |
| Online Access: | https://hdl.handle.net/2445/125567 |
| Access Level: | Open access |
| Keyword: | Pal·ladi (Element químic) Voltametria Palladium Voltammetry |
| Summary: | The use of an antimony film coated on a screen-printed carbon electrode (ex-situ SbSPCE) is proposed for the determination of Pd(II) at ppb levels in natural samples by adsorptive stripping voltammetry using dimethylglyoxime as chelating agent. Ex-situ SbSPCE produces a better analytical performance as compared to a commercially sputtered bismuth screen-printed electrode (BispSPE). The detection and quantification limits were 2.7 and 9.0 µg L-1 respectively with a good linear behaviour in the wide examined concentration range (from 1 µg L-1 up to 100.0 µg L1, R2= 0.998). The proposed ex-situ SbSPCE showed an excellent repeatability with a relative standard deviation of 0.5 % for ten successive measurements and a very good reproducibility (1.6 % for three different ex-situ SbSPCE units within series of ten repetitive assays). Moreover, the ex-situ SbSPCE was successfully applied for the determination of low concentration levels of Pd(II) in spiked tap water with a very high reproducibility (0.2 %) and providing equivalent results to those achieved by ICP-MS measurements |
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