Modified rule of mixtures and Halpin-Tsai models applied to PCL/NiMnInCo 4D printed composites. Internal stresses study during the martensitic transformation.

4D printing enables the manufacturing of complex smart components in a wide variety of shapes. In devices based on 4D printed composite materials, the interaction between the active microparticles and the printable polymer matrix plays a critical role for the optimal functionality. Key parameters in...

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Autores: Lambri, Fernando Daniel, Bonifacich, Federico Guillermo, Lambri, Osvaldo Agustín, Weidenfeller, B., Recarte Callado, Vicente, Sánchez-Alarcos Gómez, Vicente, Pérez de Landazábal Berganzo, José Ignacio
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2025
País:España
Institución:Universidad Pública de Navarra
Repositorio:Academica-e. Repositorio Institucional de la Universidad Pública de Navarra
OAI Identifier:oai:academica-e.unavarra.es:2454/53747
Acceso en línea:https://hdl.handle.net/2454/53747
Access Level:acceso embargado
Palabra clave:4D printing
Polymer chain flow
Internal stresses
Rule of mixture
Halpin-Tsai model
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spelling Modified rule of mixtures and Halpin-Tsai models applied to PCL/NiMnInCo 4D printed composites. Internal stresses study during the martensitic transformation.Lambri, Fernando DanielBonifacich, Federico GuillermoLambri, Osvaldo AgustínWeidenfeller, B.Recarte Callado, VicenteSánchez-Alarcos Gómez, VicentePérez de Landazábal Berganzo, José Ignacio4D printingPolymer chain flowInternal stressesRule of mixtureHalpin-Tsai model4D printing enables the manufacturing of complex smart components in a wide variety of shapes. In devices based on 4D printed composite materials, the interaction between the active microparticles and the printable polymer matrix plays a critical role for the optimal functionality. Key parameters in these materials are the elastic misfit coefficient, which monitors internal stresses, and elastic energy transfer, which determines the ability to transfer strain from the microparticles to the surrounding matrix. In this work, the temperature-dependent shear modulus of PCL/Ni45Mn36.7In13.3Co5 4D printed composites is analysed using the modified rule of mixture (ROM) and Halpin-Tsai (HT) models. The molecular flow caused by the polymer chain movement under oscillatory mechanical stress at relatively elevated temperatures is examined and discussed using these models. Additionally, the effect of an external direct magnetic field on the shear modulus is also analysed. Finally, the internal stresses in the composite materials resulting from the martensitic transformation in the active microparticles are studied through a modified mean-field model based on the Eshelby's inclusion theory.This work was partially supported by PIP-CONICET 11220210100073CO (2022-2024), the PPCT-UNR 80020220600018UR (2023-2026), the PID-UNR80020220700026UR (2023-2026), the Cooperation Agreement between the Universidad Nacional de Rosario and the Universidad Pública de Navarra, Res. C S 3812/2021 (2021-2026) and the Spanish Agencia Estatal de Investigacion (AEI), Ministerio de Ciencia e Innovacion (Project PID2022-138108OB-C32 (MCIU/AEI/FEDER, UE)).ElsevierCienciasZientziakInstitute for Advanced Materials and Mathematics - INAMAT2Universidad Pública de Navarra / Nafarroako Unibertsitate Publikoa2025info:eu-repo/semantics/articleinfo:eu-repo/semantics/acceptedVersionapplication/pdfhttps://hdl.handle.net/2454/53747reponame:Academica-e. Repositorio Institucional de la Universidad Pública de Navarrainstname:Universidad Pública de NavarraInglésinfo:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023/PID2022-138108OB-C32© 2025 Elsevier Ltd. This manuscript version is made available under the CC-BY-NC-ND 4.0.https://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/embargoedAccessoai:academica-e.unavarra.es:2454/537472026-06-17T12:41:47Z
dc.title.none.fl_str_mv Modified rule of mixtures and Halpin-Tsai models applied to PCL/NiMnInCo 4D printed composites. Internal stresses study during the martensitic transformation.
title Modified rule of mixtures and Halpin-Tsai models applied to PCL/NiMnInCo 4D printed composites. Internal stresses study during the martensitic transformation.
spellingShingle Modified rule of mixtures and Halpin-Tsai models applied to PCL/NiMnInCo 4D printed composites. Internal stresses study during the martensitic transformation.
Lambri, Fernando Daniel
4D printing
Polymer chain flow
Internal stresses
Rule of mixture
Halpin-Tsai model
title_short Modified rule of mixtures and Halpin-Tsai models applied to PCL/NiMnInCo 4D printed composites. Internal stresses study during the martensitic transformation.
title_full Modified rule of mixtures and Halpin-Tsai models applied to PCL/NiMnInCo 4D printed composites. Internal stresses study during the martensitic transformation.
title_fullStr Modified rule of mixtures and Halpin-Tsai models applied to PCL/NiMnInCo 4D printed composites. Internal stresses study during the martensitic transformation.
title_full_unstemmed Modified rule of mixtures and Halpin-Tsai models applied to PCL/NiMnInCo 4D printed composites. Internal stresses study during the martensitic transformation.
title_sort Modified rule of mixtures and Halpin-Tsai models applied to PCL/NiMnInCo 4D printed composites. Internal stresses study during the martensitic transformation.
dc.creator.none.fl_str_mv Lambri, Fernando Daniel
Bonifacich, Federico Guillermo
Lambri, Osvaldo Agustín
Weidenfeller, B.
Recarte Callado, Vicente
Sánchez-Alarcos Gómez, Vicente
Pérez de Landazábal Berganzo, José Ignacio
author Lambri, Fernando Daniel
author_facet Lambri, Fernando Daniel
Bonifacich, Federico Guillermo
Lambri, Osvaldo Agustín
Weidenfeller, B.
Recarte Callado, Vicente
Sánchez-Alarcos Gómez, Vicente
Pérez de Landazábal Berganzo, José Ignacio
author_role author
author2 Bonifacich, Federico Guillermo
Lambri, Osvaldo Agustín
Weidenfeller, B.
Recarte Callado, Vicente
Sánchez-Alarcos Gómez, Vicente
Pérez de Landazábal Berganzo, José Ignacio
author2_role author
author
author
author
author
author
dc.contributor.none.fl_str_mv Ciencias
Zientziak
Institute for Advanced Materials and Mathematics - INAMAT2
Universidad Pública de Navarra / Nafarroako Unibertsitate Publikoa
dc.subject.none.fl_str_mv 4D printing
Polymer chain flow
Internal stresses
Rule of mixture
Halpin-Tsai model
topic 4D printing
Polymer chain flow
Internal stresses
Rule of mixture
Halpin-Tsai model
description 4D printing enables the manufacturing of complex smart components in a wide variety of shapes. In devices based on 4D printed composite materials, the interaction between the active microparticles and the printable polymer matrix plays a critical role for the optimal functionality. Key parameters in these materials are the elastic misfit coefficient, which monitors internal stresses, and elastic energy transfer, which determines the ability to transfer strain from the microparticles to the surrounding matrix. In this work, the temperature-dependent shear modulus of PCL/Ni45Mn36.7In13.3Co5 4D printed composites is analysed using the modified rule of mixture (ROM) and Halpin-Tsai (HT) models. The molecular flow caused by the polymer chain movement under oscillatory mechanical stress at relatively elevated temperatures is examined and discussed using these models. Additionally, the effect of an external direct magnetic field on the shear modulus is also analysed. Finally, the internal stresses in the composite materials resulting from the martensitic transformation in the active microparticles are studied through a modified mean-field model based on the Eshelby's inclusion theory.
publishDate 2025
dc.date.none.fl_str_mv 2025
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/acceptedVersion
format article
status_str acceptedVersion
dc.identifier.none.fl_str_mv https://hdl.handle.net/2454/53747
url https://hdl.handle.net/2454/53747
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023/PID2022-138108OB-C32
dc.rights.none.fl_str_mv © 2025 Elsevier Ltd. This manuscript version is made available under the CC-BY-NC-ND 4.0.
https://creativecommons.org/licenses/by-nc-nd/4.0/
info:eu-repo/semantics/embargoedAccess
rights_invalid_str_mv © 2025 Elsevier Ltd. This manuscript version is made available under the CC-BY-NC-ND 4.0.
https://creativecommons.org/licenses/by-nc-nd/4.0/
eu_rights_str_mv embargoedAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:Academica-e. Repositorio Institucional de la Universidad Pública de Navarra
instname:Universidad Pública de Navarra
instname_str Universidad Pública de Navarra
reponame_str Academica-e. Repositorio Institucional de la Universidad Pública de Navarra
collection Academica-e. Repositorio Institucional de la Universidad Pública de Navarra
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repository.mail.fl_str_mv
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