Pyridinium N-(2'-azinyl)aminides: Regioselective synthesis of 2-alkylaminoazines

The regioselective alkylation of pyridinium-N-(2'-azinil)aminides with alkyl halides under mild conditions is described. The alkylation, combined with a reduction of the N-N bond, allows an easy preparation of 2-alkylaminoazines.

Detalles Bibliográficos
Autores: Martínez Barrasa, Valentín, Delgado Jiménez, Francisca, Burgos García, Carolina, García Navío, José Luis, Izquierdo Ceinos, María Luisa, Álvarez-Builla Gómez, Julio
Tipo de recurso: artículo
Fecha de publicación:2000
País:España
Institución:Universidad de Alcalá (UAH)
Repositorio:e_Buah Biblioteca Digital Universidad de Alcalá
Idioma:inglés
OAI Identifier:oai:ebuah.uah.es:10017/3426
Acceso en línea:http://hdl.handle.net/10017/3426
https://dx.doi.org/10.1016/S0040-4020(00)00084-3
Access Level:acceso abierto
Palabra clave:Alkylation
Amidines
Pyridinium salts
Ylids
Ciencia
Química orgánica
Science
Chemistry, organic
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spelling Pyridinium N-(2'-azinyl)aminides: Regioselective synthesis of 2-alkylaminoazinesMartínez Barrasa, ValentínDelgado Jiménez, FranciscaBurgos García, CarolinaGarcía Navío, José LuisIzquierdo Ceinos, María LuisaÁlvarez-Builla Gómez, JulioAlkylationAmidinesPyridinium saltsYlidsCienciaQuímica orgánicaScienceChemistry, organicThe regioselective alkylation of pyridinium-N-(2'-azinil)aminides with alkyl halides under mild conditions is described. The alkylation, combined with a reduction of the N-N bond, allows an easy preparation of 2-alkylaminoazines.The authors wish to thank the Comision Interministerial de Ciencia y Tecnologı́a (C.I.C.Y.T.) (Project PM97-0074) and the Vicerrectorado de Investigación, Universidad de Alcalá for financial support (Project E014/97).Comisión Interministerial de Ciencia y Tecnología-CICYTUniversidad de AlcaláPergamon20002000-01-01journal articlehttp://purl.org/coar/resource_type/c_6501NAhttp://purl.org/coar/version/c_be7fb7dd8ff6fe43info:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10017/3426https://dx.doi.org/10.1016/S0040-4020(00)00084-3reponame:e_Buah Biblioteca Digital Universidad de Alcaláinstname:Universidad de Alcalá (UAH)InglésengCICYT Not available PM97-0074 N-AMINIDAS DE AZINIO Y AZOLIO E INTERMEDIOS 1,3-DIPOLARES EN LA SÍNTESIS DE SISTEMAS HETEROCICLICOS DE INTERÉS FARMACEÚTICOUAH Not available E014%2F97open accesshttp://purl.org/coar/access_right/c_abf2Attribution-NonCommercial-NoDerivatives 4.0 Internationalhttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessoai:ebuah.uah.es:10017/34262026-06-18T11:13:07Z
dc.title.none.fl_str_mv Pyridinium N-(2'-azinyl)aminides: Regioselective synthesis of 2-alkylaminoazines
title Pyridinium N-(2'-azinyl)aminides: Regioselective synthesis of 2-alkylaminoazines
spellingShingle Pyridinium N-(2'-azinyl)aminides: Regioselective synthesis of 2-alkylaminoazines
Martínez Barrasa, Valentín
Alkylation
Amidines
Pyridinium salts
Ylids
Ciencia
Química orgánica
Science
Chemistry, organic
title_short Pyridinium N-(2'-azinyl)aminides: Regioselective synthesis of 2-alkylaminoazines
title_full Pyridinium N-(2'-azinyl)aminides: Regioselective synthesis of 2-alkylaminoazines
title_fullStr Pyridinium N-(2'-azinyl)aminides: Regioselective synthesis of 2-alkylaminoazines
title_full_unstemmed Pyridinium N-(2'-azinyl)aminides: Regioselective synthesis of 2-alkylaminoazines
title_sort Pyridinium N-(2'-azinyl)aminides: Regioselective synthesis of 2-alkylaminoazines
dc.creator.none.fl_str_mv Martínez Barrasa, Valentín
Delgado Jiménez, Francisca
Burgos García, Carolina
García Navío, José Luis
Izquierdo Ceinos, María Luisa
Álvarez-Builla Gómez, Julio
author Martínez Barrasa, Valentín
author_facet Martínez Barrasa, Valentín
Delgado Jiménez, Francisca
Burgos García, Carolina
García Navío, José Luis
Izquierdo Ceinos, María Luisa
Álvarez-Builla Gómez, Julio
author_role author
author2 Delgado Jiménez, Francisca
Burgos García, Carolina
García Navío, José Luis
Izquierdo Ceinos, María Luisa
Álvarez-Builla Gómez, Julio
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Alkylation
Amidines
Pyridinium salts
Ylids
Ciencia
Química orgánica
Science
Chemistry, organic
topic Alkylation
Amidines
Pyridinium salts
Ylids
Ciencia
Química orgánica
Science
Chemistry, organic
description The regioselective alkylation of pyridinium-N-(2'-azinil)aminides with alkyl halides under mild conditions is described. The alkylation, combined with a reduction of the N-N bond, allows an easy preparation of 2-alkylaminoazines.
publishDate 2000
dc.date.none.fl_str_mv 2000
2000-01-01
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
NA
http://purl.org/coar/version/c_be7fb7dd8ff6fe43
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv http://hdl.handle.net/10017/3426
https://dx.doi.org/10.1016/S0040-4020(00)00084-3
url http://hdl.handle.net/10017/3426
https://dx.doi.org/10.1016/S0040-4020(00)00084-3
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.relation.none.fl_str_mv CICYT Not available PM97-0074 N-AMINIDAS DE AZINIO Y AZOLIO E INTERMEDIOS 1,3-DIPOLARES EN LA SÍNTESIS DE SISTEMAS HETEROCICLICOS DE INTERÉS FARMACEÚTICO
UAH Not available E014%2F97
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Pergamon
publisher.none.fl_str_mv Pergamon
dc.source.none.fl_str_mv reponame:e_Buah Biblioteca Digital Universidad de Alcalá
instname:Universidad de Alcalá (UAH)
instname_str Universidad de Alcalá (UAH)
reponame_str e_Buah Biblioteca Digital Universidad de Alcalá
collection e_Buah Biblioteca Digital Universidad de Alcalá
repository.name.fl_str_mv
repository.mail.fl_str_mv
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