Stable isotope variations in arc lavas

Subduction zones are unique tectonic setting in our solar system that facilitate crustal recycling and play a key role in the generation of continental crust, element transport and volatile cycling. The geochemistry of arc lavas produced at subduction zones has long been used to untangle the complex...

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Detalles Bibliográficos
Autores: Prytulak, Julie, König, Stephan
Tipo de recurso: otro
Estado:Versión aceptada para publicación
Fecha de publicación:2025
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/404792
Acceso en línea:http://hdl.handle.net/10261/404792
https://doi.org/10.1016/B978-0-323-99762-1.00118-2
Access Level:acceso abierto
Palabra clave:Arc magma
Co-ordination
Degassing
Dehydration
Fractional crystallization
Fractionation factor
Mantle heterogeneity
Oxygen fugacity
Partial melting
Phengite
Residual slab
Rutile
Sediment recycling
Serpentine
Slab fluids
Stable isotope
Subduction
Volatile cycling
Descripción
Sumario:Subduction zones are unique tectonic setting in our solar system that facilitate crustal recycling and play a key role in the generation of continental crust, element transport and volatile cycling. The geochemistry of arc lavas produced at subduction zones has long been used to untangle the complex interplay of processes on both local and global scales. The past few decades have witnessed an explosion in the exploitation of stable isotope ratios to investigate arc lavas, enabled by step changes in analytical capabilities. This chapter reviews the rapidly evolving field of stable isotope geochemistry as applied to arc lavas. The entire periodic table is analytically accessible, however, there is great disparity in our understanding of individual isotope systems in arcs. Some have been explored for decades (e.g., B), some have sufficient data to test hypotheses (e.g., Fe, Tl, Mo) and some remain unexplored (e.g., Ni, Cr). The emerging picture is one of greater isotopic variability of many, but not all, primitive arc lavas compared to mid-ocean ridge basalts. When present, variations allow quantification of arc lava ‘ingredients,’ alongside understanding dynamic processes such as serpentinization, fluid fluxes and compositions, evolving redox conditions, and the control of accessory phases. Combining advances in stable isotope geochemistry with multi-disciplinary information from geophysics, tectonics, petrology will allow exciting breakthroughs in identifying and quantifying processes taking place at the most critical locations for mass transfer on our planet.