Catalytic dehydrogenative coupling of hydrosilanes with alcohols for the production of hydrogen on-demand: Application of the pair silane/alcohol as liquid organic hydrogen carrier

The compound [Ru(p‐cym)(Cl)2(NHC)] is an effective catalyst for the room‐temperature coupling of silanes and alcohols with the concomitant formation of molecular hydrogen. High catalyst activity is observed for a variety of substrates affording quantitative yields in minutes at room temperature and...

Descripción completa

Detalles Bibliográficos
Autores: Ventura Espinosa, David, Carretero-Cerdán, Alba, Baya, Miguel, García Gómez, Hermenegildo, Mata, José A.
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2017
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/184979
Acceso en línea:http://hdl.handle.net/10261/184979
Access Level:acceso abierto
id ES_52691f14e9fd4e301595ce4532fc0fb5
oai_identifier_str oai:digital.csic.es:10261/184979
network_acronym_str ES
network_name_str España
repository_id_str
spelling Catalytic dehydrogenative coupling of hydrosilanes with alcohols for the production of hydrogen on-demand: Application of the pair silane/alcohol as liquid organic hydrogen carrierVentura Espinosa, DavidCarretero-Cerdán, AlbaBaya, MiguelGarcía Gómez, HermenegildoMata, José A.The compound [Ru(p‐cym)(Cl)2(NHC)] is an effective catalyst for the room‐temperature coupling of silanes and alcohols with the concomitant formation of molecular hydrogen. High catalyst activity is observed for a variety of substrates affording quantitative yields in minutes at room temperature and with a catalyst loading as low as 0.1 mol %. The coupling reaction is thermodynamically and, in the presence of a Ru complex, kinetically favourable and allows rapid molecular hydrogen generation on‐demand at room temperature, under air, and without any additive. The pair silane/alcohol is a potential liquid organic hydrogen carrier (LOHC) for energy storage over long periods in a safe and secure way. Silanes and alcohols are non‐toxic compounds and do not require special handling precautions such as high pressure or an inert atmosphere. These properties enhance the practical applications of the pair silane/alcohol as a good LOHC in the automotive industry. The variety and availability of silanes and alcohols permits a pair combination that fulfils the requirements for developing an efficient LOHC.The authors thank the financial support from MINECO (CTQ2015‐69153‐C2‐1‐R, CTQ2015‐69153‐C2‐2‐R and CTQ2015‐67461‐P), Generalitat Valenciana (AICO/2015/039), Diputación General de Aragón (Grupo Consolidado E21) and Universitat Jaume I (P1.1B2015‐09). D. V‐E thanks the MINECO for the FPU grant (FPU15/03011).Peer reviewedWiley-VCHMinisterio de Economía y Competitividad (España)Diputación General de AragónGeneralitat ValencianaUniversidad Jaime IConsejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]201920192017info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Postprintinfo:eu-repo/semantics/acceptedVersionhttp://hdl.handle.net/10261/184979reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Inglés#PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE#info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2015‐69153‐C2‐1‐Rinfo:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2015‐69153‐C2‐2‐Rinfo:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2015‐67461‐Phttps://doi.org/10.1002/chem.201700243Síinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/1849792026-05-22T06:33:51Z
dc.title.none.fl_str_mv Catalytic dehydrogenative coupling of hydrosilanes with alcohols for the production of hydrogen on-demand: Application of the pair silane/alcohol as liquid organic hydrogen carrier
title Catalytic dehydrogenative coupling of hydrosilanes with alcohols for the production of hydrogen on-demand: Application of the pair silane/alcohol as liquid organic hydrogen carrier
spellingShingle Catalytic dehydrogenative coupling of hydrosilanes with alcohols for the production of hydrogen on-demand: Application of the pair silane/alcohol as liquid organic hydrogen carrier
Ventura Espinosa, David
title_short Catalytic dehydrogenative coupling of hydrosilanes with alcohols for the production of hydrogen on-demand: Application of the pair silane/alcohol as liquid organic hydrogen carrier
title_full Catalytic dehydrogenative coupling of hydrosilanes with alcohols for the production of hydrogen on-demand: Application of the pair silane/alcohol as liquid organic hydrogen carrier
title_fullStr Catalytic dehydrogenative coupling of hydrosilanes with alcohols for the production of hydrogen on-demand: Application of the pair silane/alcohol as liquid organic hydrogen carrier
title_full_unstemmed Catalytic dehydrogenative coupling of hydrosilanes with alcohols for the production of hydrogen on-demand: Application of the pair silane/alcohol as liquid organic hydrogen carrier
title_sort Catalytic dehydrogenative coupling of hydrosilanes with alcohols for the production of hydrogen on-demand: Application of the pair silane/alcohol as liquid organic hydrogen carrier
dc.creator.none.fl_str_mv Ventura Espinosa, David
Carretero-Cerdán, Alba
Baya, Miguel
García Gómez, Hermenegildo
Mata, José A.
author Ventura Espinosa, David
author_facet Ventura Espinosa, David
Carretero-Cerdán, Alba
Baya, Miguel
García Gómez, Hermenegildo
Mata, José A.
author_role author
author2 Carretero-Cerdán, Alba
Baya, Miguel
García Gómez, Hermenegildo
Mata, José A.
author2_role author
author
author
author
dc.contributor.none.fl_str_mv Ministerio de Economía y Competitividad (España)
Diputación General de Aragón
Generalitat Valenciana
Universidad Jaime I
Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]
description The compound [Ru(p‐cym)(Cl)2(NHC)] is an effective catalyst for the room‐temperature coupling of silanes and alcohols with the concomitant formation of molecular hydrogen. High catalyst activity is observed for a variety of substrates affording quantitative yields in minutes at room temperature and with a catalyst loading as low as 0.1 mol %. The coupling reaction is thermodynamically and, in the presence of a Ru complex, kinetically favourable and allows rapid molecular hydrogen generation on‐demand at room temperature, under air, and without any additive. The pair silane/alcohol is a potential liquid organic hydrogen carrier (LOHC) for energy storage over long periods in a safe and secure way. Silanes and alcohols are non‐toxic compounds and do not require special handling precautions such as high pressure or an inert atmosphere. These properties enhance the practical applications of the pair silane/alcohol as a good LOHC in the automotive industry. The variety and availability of silanes and alcohols permits a pair combination that fulfils the requirements for developing an efficient LOHC.
publishDate 2017
dc.date.none.fl_str_mv 2017
2019
2019
dc.type.none.fl_str_mv info:eu-repo/semantics/article
http://purl.org/coar/resource_type/c_6501
Postprint
info:eu-repo/semantics/acceptedVersion
format article
status_str acceptedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10261/184979
url http://hdl.handle.net/10261/184979
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv #PLACEHOLDER_PARENT_METADATA_VALUE#
#PLACEHOLDER_PARENT_METADATA_VALUE#
#PLACEHOLDER_PARENT_METADATA_VALUE#
info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2015‐69153‐C2‐1‐R
info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2015‐69153‐C2‐2‐R
info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2015‐67461‐P
https://doi.org/10.1002/chem.201700243
Sí
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv Wiley-VCH
publisher.none.fl_str_mv Wiley-VCH
dc.source.none.fl_str_mv reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC
instname:Consejo Superior de Investigaciones Científicas (CSIC)
instname_str Consejo Superior de Investigaciones Científicas (CSIC)
reponame_str DIGITAL.CSIC. Repositorio Institucional del CSIC
collection DIGITAL.CSIC. Repositorio Institucional del CSIC
repository.name.fl_str_mv
repository.mail.fl_str_mv
_version_ 1869408029570498560
score 15,811543

Similares en LA Referencia