A non-destructive sampling method for food authentication using gas chromatography coupled to mass spectrometry or ion mobility spectrometry

The study of volatile compounds obtained by gas chromatography (GC) coupled to mass spectrometry (MS) or ion mobility spectrometry (IMS) may be very useful to protect food quality, especially when using a non-destructive sampling method. In this work, the authentication of the highly appreciated dry...

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Detalhes bibliográficos
Autores: Segura Borrego, María del Pilar, Martín-Gómez, A., Ríos-Reina, Rocío, Cardador, M. J., Morales Gómez, María Lourdes, Arce, L., Callejón Fernández, Raquel María
Tipo de documento: artigo
Estado:Versión aceptada para publicación
Data de publicação:2022
País:España
Recursos:Universidad de Sevilla (US)
Repositório:idUS. Depósito de Investigación de la Universidad de Sevilla
OAI Identifier:oai:dnet:idus________::ae689ad883615de7cc8aef933ff2b65d
Acesso em linha:https://hdl.handle.net/11441/185594
https://doi.org/10.1016/j.foodchem.2021.131540
Access Level:Acceso aberto
Palavra-chave:Dry-cured Iberian ham
HS-GC-MS
HS-GC-IMS
Acorn-fed
Feed-fed
Non-destructive sampling
Descrição
Resumo:The study of volatile compounds obtained by gas chromatography (GC) coupled to mass spectrometry (MS) or ion mobility spectrometry (IMS) may be very useful to protect food quality, especially when using a non-destructive sampling method. In this work, the authentication of the highly appreciated dry-cured Iberian ham by those techniques was studied and compared. The results obtained show the suitability of a non-destructive sampling method coupled to headspace sampling (HS)-GC-IMS or HS-GC–MS to determine volatile markers in the feeding Iberian pig regime. Although both methods were suitable to differentiate the ham categories, HS-GC-IMS was more sensitive detecting a higher number of compounds than HS-GC–MS, which provided accurate qualitative results. The results of principal component analysis showed that ethanol, 2-propanol and 3-methylbutanol, identified by HS-GC-IMS, and 3-methylbutanal and heptane, identified by HS-GC–MS, could be considered potential markers to identify ham from different feeding regimes.