Photon upconversion crystals doped bacterial cellulose composite films as recyclable photonic bioplastics

Biopolymers currently utilized as substitutes for synthetic polymers in photonics applications are predominantly confined to linear optical color responses. Herein we expand their applications in non-linear optics by integrating with triplet-triplet annihilation photon upconversion crystals. A photo...

Descripción completa

Detalles Bibliográficos
Autores: Bharmoria, Pankaj|||0000-0001-6573-0475, Naimovičius, Lukas|||0000-0002-3358-4108, Abol-Fotouh, Deyaa|||0000-0003-4505-5534, Miroshnichenko, Mila, Lekavičius, Justas|||0009-0002-3361-8088, De Luca, Gabriele|||0000-0003-3757-3761, Saeed, Umair|||0000-0001-7397-9123, Kazlauskas, Karolis, Candau, Nicolas|||0000-0002-1559-8696, Baronas, Pauliu., Roig i Serra, Anna|||0000-0001-6464-7573, Moth-Poulsen, Kasper|||0000-0003-4018-4927
Tipo de recurso: artículo
Fecha de publicación:2024
País:España
Institución:Universitat Autònoma de Barcelona
Repositorio:Dipòsit Digital de Documents de la UAB
Idioma:inglés
OAI Identifier:oai:ddd.uab.cat:302513
Acceso en línea:https://ddd.uab.cat/record/302513
https://dx.doi.org/urn:doi:10.1038/s43246-024-00638-6
Access Level:acceso abierto
id ES_51a688ccaa1ec0cbebf51fe6be4db75a
oai_identifier_str oai:ddd.uab.cat:302513
network_acronym_str ES
network_name_str España
repository_id_str
spelling Photon upconversion crystals doped bacterial cellulose composite films as recyclable photonic bioplasticsBharmoria, Pankaj|||0000-0001-6573-0475Naimovičius, Lukas|||0000-0002-3358-4108Abol-Fotouh, Deyaa|||0000-0003-4505-5534Miroshnichenko, MilaLekavičius, Justas|||0009-0002-3361-8088De Luca, Gabriele|||0000-0003-3757-3761Saeed, Umair|||0000-0001-7397-9123Kazlauskas, KarolisCandau, Nicolas|||0000-0002-1559-8696Baronas, Pauliu.Roig i Serra, Anna|||0000-0001-6464-7573Moth-Poulsen, Kasper|||0000-0003-4018-4927Biopolymers currently utilized as substitutes for synthetic polymers in photonics applications are predominantly confined to linear optical color responses. Herein we expand their applications in non-linear optics by integrating with triplet-triplet annihilation photon upconversion crystals. A photon upconverting biomaterial is prepared by cultivating Pd(II) meso-tetraphenyl tetrabenzoporphine: 9,10-diphenyl anthracene (sensitizer: annihilator) crystals on bacterial cellulose hydrogel that serves both as host and template for the crystallization of photon upconversion chromophores. Coating with gelatin improves the material's optical transparency by adjusting the refractive indices. The prepared material shows an upconversion of 633 nm red light to 443 nm blue light, indicated by quadratic to linear dependence on excitation power density (non-linearly). Notably, components of this material are physically dis-assembled to retrieve 66 ± 1% of annihilator, at the end of life. Whereas, the residual clean biomass is subjected to biodegradation, showcasing the sustainability of the developed photonics material. 22024-01-0120242024-01-01Articlehttp://purl.org/coar/resource_type/c_6501VoRhttp://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleapplication/pdfhttps://ddd.uab.cat/record/302513https://dx.doi.org/urn:doi:10.1038/s43246-024-00638-6reponame:Dipòsit Digital de Documents de la UABinstname:Universitat Autònoma de BarcelonaIngléseng"la Caixa" Foundation https://doi.org/10.13039/100010434 100010434Agencia Estatal de Investigación https://doi.org/10.13039/501100011033 CEX2023-001263-SAgencia Estatal de Investigación https://doi.org/10.13039/501100011033 PID2021-123873NB-I00European Commission https://doi.org/10.13039/501100000780 101002131European Commission https://doi.org/10.13039/501100000780 951801Agencia Estatal de Investigación https://doi.org/10.13039/501100011033 PID2021-122645OB-I00Agencia Estatal de Investigación https://doi.org/10.13039/501100011033 CEX2019-000917Agència de Gestió d'Ajuts Universitaris i de Recerca https://doi.org/10.13039/501100003030 2021/SGR-00446Agència de Gestió d'Ajuts Universitaris i de Recerca https://doi.org/10.13039/501100003030 2021/SGR-01042Agencia Estatal de Investigación https://doi.org/10.13039/501100011033 RYC2021-032524-Iopen accesshttp://purl.org/coar/access_right/c_abf2Aquest document està subjecte a una llicència d'ús Creative Commons. Es permet la reproducció total o parcial, la distribució, la comunicació pública de l'obra i la creació d'obres derivades, fins i tot amb finalitats comercials, sempre i quan es reconegui l'autoria de l'obra original.https://creativecommons.org/licenses/by/4.0/info:eu-repo/semantics/openAccessoai:ddd.uab.cat:3025132026-06-06T12:50:31Z
dc.title.none.fl_str_mv Photon upconversion crystals doped bacterial cellulose composite films as recyclable photonic bioplastics
title Photon upconversion crystals doped bacterial cellulose composite films as recyclable photonic bioplastics
spellingShingle Photon upconversion crystals doped bacterial cellulose composite films as recyclable photonic bioplastics
Bharmoria, Pankaj|||0000-0001-6573-0475
title_short Photon upconversion crystals doped bacterial cellulose composite films as recyclable photonic bioplastics
title_full Photon upconversion crystals doped bacterial cellulose composite films as recyclable photonic bioplastics
title_fullStr Photon upconversion crystals doped bacterial cellulose composite films as recyclable photonic bioplastics
title_full_unstemmed Photon upconversion crystals doped bacterial cellulose composite films as recyclable photonic bioplastics
title_sort Photon upconversion crystals doped bacterial cellulose composite films as recyclable photonic bioplastics
dc.creator.none.fl_str_mv Bharmoria, Pankaj|||0000-0001-6573-0475
Naimovičius, Lukas|||0000-0002-3358-4108
Abol-Fotouh, Deyaa|||0000-0003-4505-5534
Miroshnichenko, Mila
Lekavičius, Justas|||0009-0002-3361-8088
De Luca, Gabriele|||0000-0003-3757-3761
Saeed, Umair|||0000-0001-7397-9123
Kazlauskas, Karolis
Candau, Nicolas|||0000-0002-1559-8696
Baronas, Pauliu.
Roig i Serra, Anna|||0000-0001-6464-7573
Moth-Poulsen, Kasper|||0000-0003-4018-4927
author Bharmoria, Pankaj|||0000-0001-6573-0475
author_facet Bharmoria, Pankaj|||0000-0001-6573-0475
Naimovičius, Lukas|||0000-0002-3358-4108
Abol-Fotouh, Deyaa|||0000-0003-4505-5534
Miroshnichenko, Mila
Lekavičius, Justas|||0009-0002-3361-8088
De Luca, Gabriele|||0000-0003-3757-3761
Saeed, Umair|||0000-0001-7397-9123
Kazlauskas, Karolis
Candau, Nicolas|||0000-0002-1559-8696
Baronas, Pauliu.
Roig i Serra, Anna|||0000-0001-6464-7573
Moth-Poulsen, Kasper|||0000-0003-4018-4927
author_role author
author2 Naimovičius, Lukas|||0000-0002-3358-4108
Abol-Fotouh, Deyaa|||0000-0003-4505-5534
Miroshnichenko, Mila
Lekavičius, Justas|||0009-0002-3361-8088
De Luca, Gabriele|||0000-0003-3757-3761
Saeed, Umair|||0000-0001-7397-9123
Kazlauskas, Karolis
Candau, Nicolas|||0000-0002-1559-8696
Baronas, Pauliu.
Roig i Serra, Anna|||0000-0001-6464-7573
Moth-Poulsen, Kasper|||0000-0003-4018-4927
author2_role author
author
author
author
author
author
author
author
author
author
author
description Biopolymers currently utilized as substitutes for synthetic polymers in photonics applications are predominantly confined to linear optical color responses. Herein we expand their applications in non-linear optics by integrating with triplet-triplet annihilation photon upconversion crystals. A photon upconverting biomaterial is prepared by cultivating Pd(II) meso-tetraphenyl tetrabenzoporphine: 9,10-diphenyl anthracene (sensitizer: annihilator) crystals on bacterial cellulose hydrogel that serves both as host and template for the crystallization of photon upconversion chromophores. Coating with gelatin improves the material's optical transparency by adjusting the refractive indices. The prepared material shows an upconversion of 633 nm red light to 443 nm blue light, indicated by quadratic to linear dependence on excitation power density (non-linearly). Notably, components of this material are physically dis-assembled to retrieve 66 ± 1% of annihilator, at the end of life. Whereas, the residual clean biomass is subjected to biodegradation, showcasing the sustainability of the developed photonics material.
publishDate 2024
dc.date.none.fl_str_mv 2
2024-01-01
2024
2024-01-01
dc.type.none.fl_str_mv Article
http://purl.org/coar/resource_type/c_6501
VoR
http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://ddd.uab.cat/record/302513
https://dx.doi.org/urn:doi:10.1038/s43246-024-00638-6
url https://ddd.uab.cat/record/302513
https://dx.doi.org/urn:doi:10.1038/s43246-024-00638-6
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.relation.none.fl_str_mv "la Caixa" Foundation https://doi.org/10.13039/100010434 100010434
Agencia Estatal de Investigación https://doi.org/10.13039/501100011033 CEX2023-001263-S
Agencia Estatal de Investigación https://doi.org/10.13039/501100011033 PID2021-123873NB-I00
European Commission https://doi.org/10.13039/501100000780 101002131
European Commission https://doi.org/10.13039/501100000780 951801
Agencia Estatal de Investigación https://doi.org/10.13039/501100011033 PID2021-122645OB-I00
Agencia Estatal de Investigación https://doi.org/10.13039/501100011033 CEX2019-000917
Agència de Gestió d'Ajuts Universitaris i de Recerca https://doi.org/10.13039/501100003030 2021/SGR-00446
Agència de Gestió d'Ajuts Universitaris i de Recerca https://doi.org/10.13039/501100003030 2021/SGR-01042
Agencia Estatal de Investigación https://doi.org/10.13039/501100011033 RYC2021-032524-I
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
https://creativecommons.org/licenses/by/4.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
https://creativecommons.org/licenses/by/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv reponame:Dipòsit Digital de Documents de la UAB
instname:Universitat Autònoma de Barcelona
instname_str Universitat Autònoma de Barcelona
reponame_str Dipòsit Digital de Documents de la UAB
collection Dipòsit Digital de Documents de la UAB
repository.name.fl_str_mv
repository.mail.fl_str_mv
_version_ 1869407979359436800
score 15.812429

Similares en LA Referencia