Fine-tuning of polarized hydroxyapatite for the catalytic conversion of dinitrogen to ammonium under mild conditions
Polarized hydroxyapatite (p-HAp), a calcium phosphate catalyst obtained at high temperature under intense electric field, has been used for the synthesis of ammonium starting from N2 and liquid water at low pressure (<6 bar) and temperatures below 120 °C. The success of the nitrogen fixation proc...
| Autores: | , , , , |
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| Formato: | artículo |
| Fecha de publicación: | 2022 |
| País: | España |
| Recursos: | Universitat Politècnica de Catalunya (UPC) |
| Repositorio: | UPCommons. Portal del coneixement obert de la UPC |
| Idioma: | inglés |
| OAI Identifier: | oai:upcommons.upc.edu:2117/377181 |
| Acesso em linha: | https://hdl.handle.net/2117/377181 https://dx.doi.org/10.1016/j.cej.2022.137440 |
| Access Level: | acceso abierto |
| Palavra-chave: | Catalysis Catàlisi Àrees temàtiques de la UPC::Enginyeria química |
| Resumo: | Polarized hydroxyapatite (p-HAp), a calcium phosphate catalyst obtained at high temperature under intense electric field, has been used for the synthesis of ammonium starting from N2 and liquid water at low pressure (<6 bar) and temperatures below 120 °C. The success of the nitrogen fixation process has been demonstrated by isotope labelling experiments using 15N2. Considering the optimal reaction conditions for the production of ammonium, the yield is as high as 154.6 ± 25.8 µmol/g of catalyst. The proposed synthesis exhibits three important advantages for its utilization in green chemistry environmental processes related to the recycling of polluted air. These are: i) the catalysts converts CO2 into valuable chemical products in addition of transforming N2 in ammonium; ii) the final energy balance is very favorable since no external electrical field is necessary to promote nitrogen and carbon fixation reactions; and iii) products are easily transferred to water favoring their extraction and avoiding the saturation of the catalyst. |
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