Stereoselective LC-MS/MS methodologies for environmental analysis of chiral pesticides

Chiral pesticides can exert stereospecific toxicity in contaminated environmental compartments. Therefore, measuring pesticides at the enantiomeric level is essential to assess the risk posed to exposed organisms, including humans. In recent years, there has been rapid progress on the development an...

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Detalles Bibliográficos
Autores: Petrie, Bruce, Camacho Muñoz, María Dolores, Martín Bueno, Julia
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2019
País:España
Institución:Universidad de Sevilla (US)
Repositorio:idUS. Depósito de Investigación de la Universidad de Sevilla
OAI Identifier:oai:idus.us.es:11441/133632
Acceso en línea:https://hdl.handle.net/11441/133632
https://doi.org/10.1016/j.trac.2018.11.010
Access Level:acceso abierto
Palabra clave:Chiral
Enantiomer
Environment
Fungicide
Herbicide
Insecticide
LC–MS/MS
Multi-residue
Pesticide
Polysaccharide
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spelling Stereoselective LC-MS/MS methodologies for environmental analysis of chiral pesticidesPetrie, BruceCamacho Muñoz, María DoloresMartín Bueno, JuliaChiralEnantiomerEnvironmentFungicideHerbicideInsecticideLC–MS/MSMulti-residuePesticidePolysaccharideChiral pesticides can exert stereospecific toxicity in contaminated environmental compartments. Therefore, measuring pesticides at the enantiomeric level is essential to assess the risk posed to exposed organisms, including humans. In recent years, there has been rapid progress on the development and application of stereoselective liquid chromatography–tandem mass spectrometry (LC–MS/MS) methodologies for monitoring pesticides in the environment. Coupling chiral LC separations with MS/MS detection enables trace enantiomeric determination of pesticides in complex environmental matrices. The intent of this review is to provide an up-to-date synopsis on recent advances of stereoselective LC–MS/MS methodologies for pesticide analysis. Key aspects of these methodologies discussed include sample storage and extraction method, stationary phases for separation, multi-residue separations, and method of quantitation. Finally, future trends in this rapidly growing field of analytical chemistry research are outlined.Premio Mensual Publicación Científica Destacada de la US. Escuela Politécnica SuperiorElsevierQuímica Analítica2019info:eu-repo/semantics/articleinfo:eu-repo/semantics/acceptedVersionapplication/pdfapplication/pdfhttps://hdl.handle.net/11441/133632https://doi.org/10.1016/j.trac.2018.11.010reponame:idUS. Depósito de Investigación de la Universidad de Sevillainstname:Universidad de Sevilla (US)InglésTrAC - Trends in Analytical Chemistry, 110, 249-258.https://doi.org/10.1016/j.trac.2018.11.010info:eu-repo/semantics/openAccessoai:idus.us.es:11441/1336322026-06-17T12:51:07Z
dc.title.none.fl_str_mv Stereoselective LC-MS/MS methodologies for environmental analysis of chiral pesticides
title Stereoselective LC-MS/MS methodologies for environmental analysis of chiral pesticides
spellingShingle Stereoselective LC-MS/MS methodologies for environmental analysis of chiral pesticides
Petrie, Bruce
Chiral
Enantiomer
Environment
Fungicide
Herbicide
Insecticide
LC–MS/MS
Multi-residue
Pesticide
Polysaccharide
title_short Stereoselective LC-MS/MS methodologies for environmental analysis of chiral pesticides
title_full Stereoselective LC-MS/MS methodologies for environmental analysis of chiral pesticides
title_fullStr Stereoselective LC-MS/MS methodologies for environmental analysis of chiral pesticides
title_full_unstemmed Stereoselective LC-MS/MS methodologies for environmental analysis of chiral pesticides
title_sort Stereoselective LC-MS/MS methodologies for environmental analysis of chiral pesticides
dc.creator.none.fl_str_mv Petrie, Bruce
Camacho Muñoz, María Dolores
Martín Bueno, Julia
author Petrie, Bruce
author_facet Petrie, Bruce
Camacho Muñoz, María Dolores
Martín Bueno, Julia
author_role author
author2 Camacho Muñoz, María Dolores
Martín Bueno, Julia
author2_role author
author
dc.contributor.none.fl_str_mv Química Analítica
dc.subject.none.fl_str_mv Chiral
Enantiomer
Environment
Fungicide
Herbicide
Insecticide
LC–MS/MS
Multi-residue
Pesticide
Polysaccharide
topic Chiral
Enantiomer
Environment
Fungicide
Herbicide
Insecticide
LC–MS/MS
Multi-residue
Pesticide
Polysaccharide
description Chiral pesticides can exert stereospecific toxicity in contaminated environmental compartments. Therefore, measuring pesticides at the enantiomeric level is essential to assess the risk posed to exposed organisms, including humans. In recent years, there has been rapid progress on the development and application of stereoselective liquid chromatography–tandem mass spectrometry (LC–MS/MS) methodologies for monitoring pesticides in the environment. Coupling chiral LC separations with MS/MS detection enables trace enantiomeric determination of pesticides in complex environmental matrices. The intent of this review is to provide an up-to-date synopsis on recent advances of stereoselective LC–MS/MS methodologies for pesticide analysis. Key aspects of these methodologies discussed include sample storage and extraction method, stationary phases for separation, multi-residue separations, and method of quantitation. Finally, future trends in this rapidly growing field of analytical chemistry research are outlined.
publishDate 2019
dc.date.none.fl_str_mv 2019
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/acceptedVersion
format article
status_str acceptedVersion
dc.identifier.none.fl_str_mv https://hdl.handle.net/11441/133632
https://doi.org/10.1016/j.trac.2018.11.010
url https://hdl.handle.net/11441/133632
https://doi.org/10.1016/j.trac.2018.11.010
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv TrAC - Trends in Analytical Chemistry, 110, 249-258.
https://doi.org/10.1016/j.trac.2018.11.010
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:idUS. Depósito de Investigación de la Universidad de Sevilla
instname:Universidad de Sevilla (US)
instname_str Universidad de Sevilla (US)
reponame_str idUS. Depósito de Investigación de la Universidad de Sevilla
collection idUS. Depósito de Investigación de la Universidad de Sevilla
repository.name.fl_str_mv
repository.mail.fl_str_mv
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