Lubrication Properties of the Ionic Liquid Dodecyl-3 Methylimidazolium bis(trifluoromethylsulfonyl)imide

The ionic liquid (IL) dodecyl-3 methylimidazolium bis(trifluoromethylsulfonyl)imide was tested as neat lubricant and as additive (at 1 and 4 wt%) in a polar oil (diester). Tribological tests were performed using a reciprocating configuration for 90 min at 30 and 70 N, 10 Hz, 4 mm stroke length, and...

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Detalhes bibliográficos
Autores: Hernández Battez, Antolín Esteban|||0000-0003-0828-4995, Ramos Alonso, Diego, Blanco Alonso, David|||0000-0001-9549-0193, González Rodríguez, Rubén|||0000-0002-0559-0762, Fernández González, Alfonso|||0000-0001-6240-2222, Viesca Rodríguez, José Luis|||0000-0002-9838-8634
Formato: artículo
Fecha de publicación:2018
País:España
Recursos:Universidad de Oviedo (UNIOVI)
Repositorio:RUO. Repositorio Institucional de la Universidad de Oviedo
Idioma:inglés
OAI Identifier:oai:digibuo.uniovi.es:10651/46214
Acesso em linha:http://hdl.handle.net/10651/46214
https://dx.doi.org/10.1007/s11249-017-0964-z
Access Level:acceso abierto
Palavra-chave:Ionic liquid
Additive
Friction
Wear
Polar oil
Descrição
Resumo:The ionic liquid (IL) dodecyl-3 methylimidazolium bis(trifluoromethylsulfonyl)imide was tested as neat lubricant and as additive (at 1 and 4 wt%) in a polar oil (diester). Tribological tests were performed using a reciprocating configuration for 90 min at 30 and 70 N, 10 Hz, 4 mm stroke length, and at room temperature and 100 °C. Wear volume and surface–IL interaction were determined by confocal microscopy, SEM, and XPS. The main findings were: Neat ionic liquid showed the best tribological behavior; the IL-containing mixtures had similar behavior than the base oil at the lower load; meanwhile, the mixture with 4 wt% of IL outperformed the antiwear behavior of the neat base oil at the higher load; surface–IL chemical interaction was found mainly at 100 °C.