Nucleation rate and number of precipitates in V and Nb-microalloyed steels

Recrystallization-precipitation-time-temperature (RPTT) diagrams were experimentally determined for two microalloyed steels with V and Nb, respectively, at a strain of 0.35 and a strain rate of 3.63 s-1. From the RPTT diagrams, and applying the classic theory of nucleation, the nucleation rate was c...

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Detalles Bibliográficos
Autores: Medina, Sebastián F., Gómez, Manuel
Tipo de recurso: artículo
Fecha de publicación:2014
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/109665
Acceso en línea:http://hdl.handle.net/10261/109665
Access Level:acceso abierto
Palabra clave:Nucleation rate
Nucleus size
Precipitate
Microalloyed steel
Descripción
Sumario:Recrystallization-precipitation-time-temperature (RPTT) diagrams were experimentally determined for two microalloyed steels with V and Nb, respectively, at a strain of 0.35 and a strain rate of 3.63 s-1. From the RPTT diagrams, and applying the classic theory of nucleation, the nucleation rate was calculated for both steels. In order to determine the mentioned magnitudes, several parameters were calculated, such as: the Zeldovich factor (Z), the energy of formation of the nucleus (¿G), the driving force for precipitation (¿Gv), the critical radius for nucleation (Rc), and the dislocation density at the start of precipitation (¿), among others. The calculated data has made it possible to clarify the shape of precipitation start and finish curves and to plot the nucleation rate as a function of temperature. The number of precipitates was calculated by integration of the nucleation rate expression. In this way, substantial differences were established between the two types of microalloyed steels, including the final size of the V(C, N) and Nb(C, N) precipitates.