Silver-Free Au(I) Catalysis Enabled by Bifunctional Ureaand Squaramide-Phosphine Ligands via H-Bonding
old(I) chloride complexes with bifunctional phosphino(thio)urea and phosphinosquaramide ligands have been designed to be catalytically active in the absence of silver additives in intra- and intermolecular reactions of alkynes. Structure-activity relationships, DFT calculations focused on the Au−Cl...
| Autores: | , , , |
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| Tipo de recurso: | artículo |
| Estado: | Versión aceptada para publicación |
| Fecha de publicación: | 2021 |
| País: | España |
| Institución: | Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya) |
| Repositorio: | Recercat. Dipósit de la Recerca de Catalunya |
| OAI Identifier: | oai:recercat.cat:2072/521675 |
| Acceso en línea: | http://hdl.handle.net/2072/521675 https://doi.org/10.1002/chem.202101751 |
| Access Level: | acceso abierto |
| Palabra clave: | 54 |
| Sumario: | old(I) chloride complexes with bifunctional phosphino(thio)urea and phosphinosquaramide ligands have been designed to be catalytically active in the absence of silver additives in intra- and intermolecular reactions of alkynes. Structure-activity relationships, DFT calculations focused on the Au−Cl bond activation, and comprehensive kinetic studies highlight the key role of the H-bond donor group in enabling catalysis at the Au(I) center. |
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