Oxygen-Scavenging Multilayered Biopapers Containing Palladium Nanoparticles Obtained by the Electrospinning Coating Technique

[EN] The main goal of this study was to obtain, for the first time, highly efficient water barrier and oxygen-scavenging multilayered electrospun biopaper coatings of biodegradable polymers over conventional cellulose paper, using the electrospinning coating technique. In order to do so, poly(3-hydr...

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Detalles Bibliográficos
Autores: Cherpinski, Adriane, Szewczyk, Piotr K., Gruszczynski, Adam, Stachewicz, Urszula, Lagaron, Jose M.
Tipo de recurso: artículo
Fecha de publicación:2019
País:España
Institución:Universitat Politècnica de València (UPV)
Repositorio:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
Idioma:inglés
OAI Identifier:oai:riunet.upv.es:10251/202848
Acceso en línea:https://riunet.upv.es/handle/10251/202848
Access Level:acceso abierto
Palabra clave:Polyhydroxyalkanoates
Polycaprolactone
Biopapers
Palladium nanoparticles
Oxygen scavengers
Electrospinning
Fiber based packaging
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spelling Oxygen-Scavenging Multilayered Biopapers Containing Palladium Nanoparticles Obtained by the Electrospinning Coating TechniqueCherpinski, AdrianeSzewczyk, Piotr K.Gruszczynski, AdamStachewicz, UrszulaLagaron, Jose M.PolyhydroxyalkanoatesPolycaprolactoneBiopapersPalladium nanoparticlesOxygen scavengersElectrospinningFiber based packaging[EN] The main goal of this study was to obtain, for the first time, highly efficient water barrier and oxygen-scavenging multilayered electrospun biopaper coatings of biodegradable polymers over conventional cellulose paper, using the electrospinning coating technique. In order to do so, poly(3-hydroxybutyrate) (PHB) and polycaprolactone (PCL) polymer-containing palladium nanoparticles (PdNPs) were electrospun over paper, and the morphology, thermal properties, water vapor barrier, and oxygen absorption properties of nanocomposites and multilayers were investigated. In order to reduce the porosity, and to enhance the barrier properties and interlayer adhesion, the biopapers were annealed after electrospinning. A previous study showed that electrospun PHB-containing PdNP did show significant oxygen scavenging capacity, but this was strongly reduced after annealing, a process that is necessary to form a continuous film with the water barrier. The results in the current work indicate that the PdNP were better dispersed and distributed in the PCL matrix, as suggested by focus ion beam-scanning electron microscopy (FIB-SEM) experiments, and that the Pd enhanced, to some extent, the onset of PCL degradation. More importantly, the PCL/PdNP nanobiopaper exhibited much higher oxygen scavenging capacity than the homologous PHB/PdNP, due to most likely, the higher oxygen permeability of the PCL polymer and the somewhat higher dispersion of the Pd. The passive and active multilayered biopapers developed here may be of significant relevance to put forward the next generation of fully biodegradable barrier papers of interest in, for instance, food packaging.This research was funded by the Spanish Ministry of Economy and Competitiveness (MINECO) project AGL2015-63855-C2-1-R, the H2020 EU YPACK (reference number 773872) and ResUrbis (Reference number 730349). A. Cherpinski would like to thank the Brazilian Council for Scientific and Technological Development (CNPq) of the Brazilian Government for her predoctoral grant (205955/2014-2). U. Stachewicz thanks the National Science Centre in Poland for the Sonata Bis 5 project, No 2015/18/E/ST5/00230 allowing this study, and a PhD scholarship for P.K. Szewczyk.MDPI AGEuropean CommissionNational Science Centre, PoloniaMinisterio de Economía y CompetitividadConselho Nacional de Desenvolvimento Científico e Tecnológico, BrasilRepositorio Institucional de la Universitat Politècnica de València Riunet20192019-02-01journal articlehttp://purl.org/coar/resource_type/c_6501VoRhttp://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleapplication/pdfhttps://riunet.upv.es/handle/10251/202848reponame:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valénciainstname:Universitat Politècnica de València (UPV)InglésengEuropean Commission https://doi.org/10.13039/501100000780 H2020 730349European Commission https://doi.org/10.13039/501100000780 H2020 773872Ministerio de Economía y Competitividad http://dx.doi.org/10.13039/501100003329 AGL2015-63855-C2-1-R DESARROLLO DE UN CONCEPTO DE ENVASE MULTICAPA ALIMENTARIO DE ALTA BARRERA Y CON CARACTER ACTIVO Y BIOACTIVO DERIVADO DE SUBPRODUCTOS ALIMENTARIOSConselho Nacional de Desenvolvimento Científico e Tecnológico, Brasil https://doi.org/10.13039/501100003593 205955%2F2014-2National Science Centre, Polonia https://doi.org/10.13039/501100004281 2015%2F18%2FE%2FST5%2F00230open accesshttp://purl.org/coar/access_right/c_abf2Reconocimiento (by)http://creativecommons.org/licenses/by/4.0/info:eu-repo/semantics/openAccessoai:riunet.upv.es:10251/2028482026-06-13T07:49:27Z
dc.title.none.fl_str_mv Oxygen-Scavenging Multilayered Biopapers Containing Palladium Nanoparticles Obtained by the Electrospinning Coating Technique
title Oxygen-Scavenging Multilayered Biopapers Containing Palladium Nanoparticles Obtained by the Electrospinning Coating Technique
spellingShingle Oxygen-Scavenging Multilayered Biopapers Containing Palladium Nanoparticles Obtained by the Electrospinning Coating Technique
Cherpinski, Adriane
Polyhydroxyalkanoates
Polycaprolactone
Biopapers
Palladium nanoparticles
Oxygen scavengers
Electrospinning
Fiber based packaging
title_short Oxygen-Scavenging Multilayered Biopapers Containing Palladium Nanoparticles Obtained by the Electrospinning Coating Technique
title_full Oxygen-Scavenging Multilayered Biopapers Containing Palladium Nanoparticles Obtained by the Electrospinning Coating Technique
title_fullStr Oxygen-Scavenging Multilayered Biopapers Containing Palladium Nanoparticles Obtained by the Electrospinning Coating Technique
title_full_unstemmed Oxygen-Scavenging Multilayered Biopapers Containing Palladium Nanoparticles Obtained by the Electrospinning Coating Technique
title_sort Oxygen-Scavenging Multilayered Biopapers Containing Palladium Nanoparticles Obtained by the Electrospinning Coating Technique
dc.creator.none.fl_str_mv Cherpinski, Adriane
Szewczyk, Piotr K.
Gruszczynski, Adam
Stachewicz, Urszula
Lagaron, Jose M.
author Cherpinski, Adriane
author_facet Cherpinski, Adriane
Szewczyk, Piotr K.
Gruszczynski, Adam
Stachewicz, Urszula
Lagaron, Jose M.
author_role author
author2 Szewczyk, Piotr K.
Gruszczynski, Adam
Stachewicz, Urszula
Lagaron, Jose M.
author2_role author
author
author
author
dc.contributor.none.fl_str_mv European Commission
National Science Centre, Polonia
Ministerio de Economía y Competitividad
Conselho Nacional de Desenvolvimento Científico e Tecnológico, Brasil
Repositorio Institucional de la Universitat Politècnica de València Riunet
dc.subject.none.fl_str_mv Polyhydroxyalkanoates
Polycaprolactone
Biopapers
Palladium nanoparticles
Oxygen scavengers
Electrospinning
Fiber based packaging
topic Polyhydroxyalkanoates
Polycaprolactone
Biopapers
Palladium nanoparticles
Oxygen scavengers
Electrospinning
Fiber based packaging
description [EN] The main goal of this study was to obtain, for the first time, highly efficient water barrier and oxygen-scavenging multilayered electrospun biopaper coatings of biodegradable polymers over conventional cellulose paper, using the electrospinning coating technique. In order to do so, poly(3-hydroxybutyrate) (PHB) and polycaprolactone (PCL) polymer-containing palladium nanoparticles (PdNPs) were electrospun over paper, and the morphology, thermal properties, water vapor barrier, and oxygen absorption properties of nanocomposites and multilayers were investigated. In order to reduce the porosity, and to enhance the barrier properties and interlayer adhesion, the biopapers were annealed after electrospinning. A previous study showed that electrospun PHB-containing PdNP did show significant oxygen scavenging capacity, but this was strongly reduced after annealing, a process that is necessary to form a continuous film with the water barrier. The results in the current work indicate that the PdNP were better dispersed and distributed in the PCL matrix, as suggested by focus ion beam-scanning electron microscopy (FIB-SEM) experiments, and that the Pd enhanced, to some extent, the onset of PCL degradation. More importantly, the PCL/PdNP nanobiopaper exhibited much higher oxygen scavenging capacity than the homologous PHB/PdNP, due to most likely, the higher oxygen permeability of the PCL polymer and the somewhat higher dispersion of the Pd. The passive and active multilayered biopapers developed here may be of significant relevance to put forward the next generation of fully biodegradable barrier papers of interest in, for instance, food packaging.
publishDate 2019
dc.date.none.fl_str_mv 2019
2019-02-01
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
VoR
http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://riunet.upv.es/handle/10251/202848
url https://riunet.upv.es/handle/10251/202848
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.relation.none.fl_str_mv European Commission https://doi.org/10.13039/501100000780 H2020 730349
European Commission https://doi.org/10.13039/501100000780 H2020 773872
Ministerio de Economía y Competitividad http://dx.doi.org/10.13039/501100003329 AGL2015-63855-C2-1-R DESARROLLO DE UN CONCEPTO DE ENVASE MULTICAPA ALIMENTARIO DE ALTA BARRERA Y CON CARACTER ACTIVO Y BIOACTIVO DERIVADO DE SUBPRODUCTOS ALIMENTARIOS
Conselho Nacional de Desenvolvimento Científico e Tecnológico, Brasil https://doi.org/10.13039/501100003593 205955%2F2014-2
National Science Centre, Polonia https://doi.org/10.13039/501100004281 2015%2F18%2FE%2FST5%2F00230
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
Reconocimiento (by)
http://creativecommons.org/licenses/by/4.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
Reconocimiento (by)
http://creativecommons.org/licenses/by/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv MDPI AG
publisher.none.fl_str_mv MDPI AG
dc.source.none.fl_str_mv reponame:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
instname:Universitat Politècnica de València (UPV)
instname_str Universitat Politècnica de València (UPV)
reponame_str RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
collection RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,300724

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