Oxidation behavior of maraging 300 alloy exposed to nitrogen/water vapor atmosphere at 500 °C

Aging heat treatments in maraging steels are fundamental to achieve the excellent mechanical properties required in several industries, i.e., nuclear, automotive, etc. In this research, samples of maraging 300 alloy were aged using a novel procedure that combines different steps with two atmospheres...

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Detalles Bibliográficos
Autores: Cerra Flórez, Mauro Andrés|||0000-0002-0336-8463, Fargas Ribas, Gemma|||0000-0002-5106-1220, Mateo García, Antonio Manuel|||0000-0001-8336-6128, Roa Rovira, Joan Josep|||0000-0002-7440-0766
Tipo de recurso: artículo
Fecha de publicación:2021
País:España
Institución:Universitat Politècnica de Catalunya (UPC)
Repositorio:UPCommons. Portal del coneixement obert de la UPC
Idioma:inglés
OAI Identifier:oai:upcommons.upc.edu:2117/350155
Acceso en línea:https://hdl.handle.net/2117/350155
https://dx.doi.org/10.3390/met11071021
Access Level:acceso abierto
Palabra clave:Oxidation
Metals
Maraging alloy
Oxidation process
Spinel
Sliding properties
XRD study
Raman spectroscopy
Oxidació
Metalls
Àrees temàtiques de la UPC::Enginyeria dels materials::Metal·lúrgia
Descripción
Sumario:Aging heat treatments in maraging steels are fundamental to achieve the excellent mechanical properties required in several industries, i.e., nuclear, automotive, etc. In this research, samples of maraging 300 alloy were aged using a novel procedure that combines different steps with two atmospheres (nitrogen and water vapor) for several hours. The oxidized surface layer was chemical, microstructural and micromechanically characterized. Due to the thermodynamic and kinetic conditions, these gases reacted and change the surface chemistry of this steel producing a thin iron-based oxide layer of a homogeneous thickness of around 500 nm. Within the aforementioned information, porosity and other microstructural defects showed a non-homogeneous oxide, mainly constituted by magnetite, nickel ferrite, cobalt ferrite, and a small amount of hematite in the more external parts of the oxide layer. In this sense, from a chemical point of view, the heat treatment under specific atmosphere allows to induce a thin magnetic layer in a mixture of iron, nickel, and cobalt spinel ferrites. On the other hand, the oxide layer presents an adhesive force 99 mN value that shows the capability for being used for tribological applications under sliding contact tests.