Hydrogenation of amides to amines by heterogeneous catalysis: a review

[EN] Amines are pivotal building blocks for a range of applications, including pharmaceuticals, polymers, agrochemicals, and organic synthesis. The hydrogenation of amides using molecular hydrogen via heterogeneous catalysis is considered a promising method for producing amines with considerably hig...

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Autores: Yang, Huiru, Hu, Changwei, García Gómez, Hermenegildo|||0000-0002-9664-493X
Formato: artículo
Fecha de publicación:2024
País:España
Recursos:Universitat Politècnica de València (UPV)
Repositorio:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
Idioma:inglés
OAI Identifier:oai:riunet.upv.es:10251/211817
Acesso em linha:https://riunet.upv.es/handle/10251/211817
Access Level:acceso abierto
Palavra-chave:Amines
Building blocks
Pharmaceuticals
Polymers
Agrochemicals
Organic synthesis
QUIMICA ORGANICA
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spelling Hydrogenation of amides to amines by heterogeneous catalysis: a reviewYang, HuiruHu, ChangweiGarcía Gómez, Hermenegildo|||0000-0002-9664-493XAminesBuilding blocksPharmaceuticalsPolymersAgrochemicalsOrganic synthesisQUIMICA ORGANICA[EN] Amines are pivotal building blocks for a range of applications, including pharmaceuticals, polymers, agrochemicals, and organic synthesis. The hydrogenation of amides using molecular hydrogen via heterogeneous catalysis is considered a promising method for producing amines with considerably high atom efficiency, environmental friendliness, and eonomic viability. Continued developments have occurred in this area, with milestones reached in the hydrogenation of various amides to amines via heterogeneous catalysis. At present, no systematic analysis of the influence of amide structures on their reactivity and the required type of catalyst has been reported. This review describes the most recent advances in catalytic amide hydrogenation, paying special attention to the influence of structural features (cyclic amides and aliphatic acyclic amides) on catalyst performance. Structural features endow amides with specific reactivities, reflected in considerable differences in the ease of hydrogenation and diverse product selectivity. In addition, insights into the conversion of polyamides, fatty acids, and triglycerides to amines are provided. This review provides new perspectives for designing and applying heterogeneous catalysts adapted to specific conditions and amide structures. A comprehensive summary of heterogeneous catalysts for the hydrogention of various amides with differnent structural feactures to amines.This work was financially supported by the National Natural Science Foundation of China (No. 21536007) and the 111 Project (B17030). Financial support by the Spanish Ministry of Science and Innovation (CEX-2021-001230-S and PDI2021-0126071-OB-CO21 funded by MCIN/AEI/10.13039/501100011033) and Generalitat Valenciana (Prometeo 2021/038 and Advanced Materials programme Graphica MFA/2022/023 with funding from European Union NextGeneration EU PRTR-C17.I1) is gratefully acknowledged. Huiru Yang also acknowledges the support from the China Scholarship Council (CSC No. 202206240141).The Royal Society of ChemistryInstituto Universitario Mixto de Tecnología QuímicaDepartamento de QuímicaEscuela Técnica Superior de Ingeniería IndustrialGeneralitat ValencianaChina Scholarship CouncilMinistry of Education of ChinaAgencia Estatal de InvestigaciónMinisterio de Ciencia e InnovaciónNational Natural Science Foundation of ChinaRepositorio Institucional de la Universitat Politècnica de València Riunet20242024-03-04journal articlehttp://purl.org/coar/resource_type/c_6501VoRhttp://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleapplication/pdfapplication/pdfhttps://riunet.upv.es/handle/10251/211817reponame:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valénciainstname:Universitat Politècnica de València (UPV)InglésengAgencia Estatal de Investigación http://dx.doi.org/10.13039/501100011033 Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023 PID2021-126071OB-C21 APLICANDO MXENOS COMO CATALIZADORES DEFINITIVOS PARA LA PRODUCCION DE COMBUSTIBLES SOLARESNational Natural Science Foundation of China https://doi.org/10.13039/501100001809 21536007China Scholarship Council https://doi.org/10.13039/501100004543 202206240141Generalitat Valenciana https://doi.org/10.13039/501100003359 PROMETEO%2F2021%2F038Generalitat Valenciana https://doi.org/10.13039/501100003359 MFA%2F2022%2F023Ministry of Education, China https://doi.org/10.13039/501100002338 B17030 111 projectAgencia Estatal de Investigación http://dx.doi.org/10.13039/501100011033 CEX2021-001230-SMinisterio de Ciencia e Innovación http://dx.doi.org/10.13039/501100004837 PRTR-C17.I1open accesshttp://purl.org/coar/access_right/c_abf2Reserva de todos los derechoshttp://rightsstatements.org/vocab/InC/1.0/info:eu-repo/semantics/openAccessoai:riunet.upv.es:10251/2118172026-06-13T07:49:27Z
dc.title.none.fl_str_mv Hydrogenation of amides to amines by heterogeneous catalysis: a review
title Hydrogenation of amides to amines by heterogeneous catalysis: a review
spellingShingle Hydrogenation of amides to amines by heterogeneous catalysis: a review
Yang, Huiru
Amines
Building blocks
Pharmaceuticals
Polymers
Agrochemicals
Organic synthesis
QUIMICA ORGANICA
title_short Hydrogenation of amides to amines by heterogeneous catalysis: a review
title_full Hydrogenation of amides to amines by heterogeneous catalysis: a review
title_fullStr Hydrogenation of amides to amines by heterogeneous catalysis: a review
title_full_unstemmed Hydrogenation of amides to amines by heterogeneous catalysis: a review
title_sort Hydrogenation of amides to amines by heterogeneous catalysis: a review
dc.creator.none.fl_str_mv Yang, Huiru
Hu, Changwei
García Gómez, Hermenegildo|||0000-0002-9664-493X
author Yang, Huiru
author_facet Yang, Huiru
Hu, Changwei
García Gómez, Hermenegildo|||0000-0002-9664-493X
author_role author
author2 Hu, Changwei
García Gómez, Hermenegildo|||0000-0002-9664-493X
author2_role author
author
dc.contributor.none.fl_str_mv Instituto Universitario Mixto de Tecnología Química
Departamento de Química
Escuela Técnica Superior de Ingeniería Industrial
Generalitat Valenciana
China Scholarship Council
Ministry of Education of China
Agencia Estatal de Investigación
Ministerio de Ciencia e Innovación
National Natural Science Foundation of China
Repositorio Institucional de la Universitat Politècnica de València Riunet
dc.subject.none.fl_str_mv Amines
Building blocks
Pharmaceuticals
Polymers
Agrochemicals
Organic synthesis
QUIMICA ORGANICA
topic Amines
Building blocks
Pharmaceuticals
Polymers
Agrochemicals
Organic synthesis
QUIMICA ORGANICA
description [EN] Amines are pivotal building blocks for a range of applications, including pharmaceuticals, polymers, agrochemicals, and organic synthesis. The hydrogenation of amides using molecular hydrogen via heterogeneous catalysis is considered a promising method for producing amines with considerably high atom efficiency, environmental friendliness, and eonomic viability. Continued developments have occurred in this area, with milestones reached in the hydrogenation of various amides to amines via heterogeneous catalysis. At present, no systematic analysis of the influence of amide structures on their reactivity and the required type of catalyst has been reported. This review describes the most recent advances in catalytic amide hydrogenation, paying special attention to the influence of structural features (cyclic amides and aliphatic acyclic amides) on catalyst performance. Structural features endow amides with specific reactivities, reflected in considerable differences in the ease of hydrogenation and diverse product selectivity. In addition, insights into the conversion of polyamides, fatty acids, and triglycerides to amines are provided. This review provides new perspectives for designing and applying heterogeneous catalysts adapted to specific conditions and amide structures. A comprehensive summary of heterogeneous catalysts for the hydrogention of various amides with differnent structural feactures to amines.
publishDate 2024
dc.date.none.fl_str_mv 2024
2024-03-04
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
VoR
http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://riunet.upv.es/handle/10251/211817
url https://riunet.upv.es/handle/10251/211817
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.relation.none.fl_str_mv Agencia Estatal de Investigación http://dx.doi.org/10.13039/501100011033 Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023 PID2021-126071OB-C21 APLICANDO MXENOS COMO CATALIZADORES DEFINITIVOS PARA LA PRODUCCION DE COMBUSTIBLES SOLARES
National Natural Science Foundation of China https://doi.org/10.13039/501100001809 21536007
China Scholarship Council https://doi.org/10.13039/501100004543 202206240141
Generalitat Valenciana https://doi.org/10.13039/501100003359 PROMETEO%2F2021%2F038
Generalitat Valenciana https://doi.org/10.13039/501100003359 MFA%2F2022%2F023
Ministry of Education, China https://doi.org/10.13039/501100002338 B17030 111 project
Agencia Estatal de Investigación http://dx.doi.org/10.13039/501100011033 CEX2021-001230-S
Ministerio de Ciencia e Innovación http://dx.doi.org/10.13039/501100004837 PRTR-C17.I1
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
Reserva de todos los derechos
http://rightsstatements.org/vocab/InC/1.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
Reserva de todos los derechos
http://rightsstatements.org/vocab/InC/1.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv The Royal Society of Chemistry
publisher.none.fl_str_mv The Royal Society of Chemistry
dc.source.none.fl_str_mv reponame:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
instname:Universitat Politècnica de València (UPV)
instname_str Universitat Politècnica de València (UPV)
reponame_str RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
collection RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
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