Multi-Length Scale Communication Effects in Catalysis: Thinking Big and Acting Small

The use of hierarchically structured materials as catalysts has been finding increasing application in the past years. For these catalytic systems, not only the nano-scale matters: a high degree of order across multiple length scales, along with its control and analytical assessment, is of paramount...

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Autores: Moyano i Baldoire, Albert, Crusats i Aliguer, Joaquim
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2024
País:España
Institución:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Repositorio:Recercat. Dipósit de la Recerca de Catalunya
OAI Identifier:oai:recercat.cat:2445/220592
Acceso en línea:https://hdl.handle.net/2445/220592
Access Level:acceso abierto
Palabra clave:Quiralitat
Química supramolecular
Catàlisi
Chirality
Supramolecular chemistry
Catalysis
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spelling Multi-Length Scale Communication Effects in Catalysis: Thinking Big and Acting SmallMoyano i Baldoire, AlbertCrusats i Aliguer, JoaquimQuiralitatQuímica supramolecularCatàlisiChiralitySupramolecular chemistryCatalysisThe use of hierarchically structured materials as catalysts has been finding increasing application in the past years. For these catalytic systems, not only the nano-scale matters: a high degree of order across multiple length scales, along with its control and analytical assessment, is of paramount importance to obtain innovative properties that can find application in catalysis. Most reviews dealing with hierarchically structured materials are concerned with the “bottom-up” transfer of structural information along the different length scales, with special emphasis on the transmission of chirality. Due to their mesoscale size together with their complex behaviour, these systems are often susceptible to feel the effects of macroscopic forces, that can exert a “top-down” control of their catalytic properties, so that an external stimulus, acting at the level of the supramolecular architecture of the catalyst, can ultimately determine the outcome of the catalyzed reaction at the molecular level. We review in this paper some recent reports that deal with the experimental implementation of this concept, either by using a mechanical force in a full range direct transmission to the reaction coordinate, or by means of a stepwise relay transmission from the macroscopic level (purely supramolecular chirality) to the nanoscopic one. We focus in this review on these multi-length scale communication control effects, identifying the different mechanisms that are affecting the catalytic activity.Wiley-VCH2025202520242025info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersion18 p.application/pdfhttps://hdl.handle.net/2445/220592Articles publicats en revistes (Química Inorgànica i Orgànica)reponame:Recercat. Dipósit de la Recerca de Catalunyainstname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)InglésReproducció del document publicat a: https://doi.org/10.1002/adsc.202301161Advanced Synthesis & Catalysis, 2024, vol. 366, p. 617-634https://doi.org/10.1002/adsc.202301161cc-by (c) Moyano i Baldoire, Albert et al., 2024http://creativecommons.org/licenses/by/3.0/es/info:eu-repo/semantics/openAccessoai:recercat.cat:2445/2205922026-05-29T05:05:01Z
dc.title.none.fl_str_mv Multi-Length Scale Communication Effects in Catalysis: Thinking Big and Acting Small
title Multi-Length Scale Communication Effects in Catalysis: Thinking Big and Acting Small
spellingShingle Multi-Length Scale Communication Effects in Catalysis: Thinking Big and Acting Small
Moyano i Baldoire, Albert
Quiralitat
Química supramolecular
Catàlisi
Chirality
Supramolecular chemistry
Catalysis
title_short Multi-Length Scale Communication Effects in Catalysis: Thinking Big and Acting Small
title_full Multi-Length Scale Communication Effects in Catalysis: Thinking Big and Acting Small
title_fullStr Multi-Length Scale Communication Effects in Catalysis: Thinking Big and Acting Small
title_full_unstemmed Multi-Length Scale Communication Effects in Catalysis: Thinking Big and Acting Small
title_sort Multi-Length Scale Communication Effects in Catalysis: Thinking Big and Acting Small
dc.creator.none.fl_str_mv Moyano i Baldoire, Albert
Crusats i Aliguer, Joaquim
author Moyano i Baldoire, Albert
author_facet Moyano i Baldoire, Albert
Crusats i Aliguer, Joaquim
author_role author
author2 Crusats i Aliguer, Joaquim
author2_role author
dc.subject.none.fl_str_mv Quiralitat
Química supramolecular
Catàlisi
Chirality
Supramolecular chemistry
Catalysis
topic Quiralitat
Química supramolecular
Catàlisi
Chirality
Supramolecular chemistry
Catalysis
description The use of hierarchically structured materials as catalysts has been finding increasing application in the past years. For these catalytic systems, not only the nano-scale matters: a high degree of order across multiple length scales, along with its control and analytical assessment, is of paramount importance to obtain innovative properties that can find application in catalysis. Most reviews dealing with hierarchically structured materials are concerned with the “bottom-up” transfer of structural information along the different length scales, with special emphasis on the transmission of chirality. Due to their mesoscale size together with their complex behaviour, these systems are often susceptible to feel the effects of macroscopic forces, that can exert a “top-down” control of their catalytic properties, so that an external stimulus, acting at the level of the supramolecular architecture of the catalyst, can ultimately determine the outcome of the catalyzed reaction at the molecular level. We review in this paper some recent reports that deal with the experimental implementation of this concept, either by using a mechanical force in a full range direct transmission to the reaction coordinate, or by means of a stepwise relay transmission from the macroscopic level (purely supramolecular chirality) to the nanoscopic one. We focus in this review on these multi-length scale communication control effects, identifying the different mechanisms that are affecting the catalytic activity.
publishDate 2024
dc.date.none.fl_str_mv 2024
2025
2025
2025
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv https://hdl.handle.net/2445/220592
url https://hdl.handle.net/2445/220592
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv Reproducció del document publicat a: https://doi.org/10.1002/adsc.202301161
Advanced Synthesis & Catalysis, 2024, vol. 366, p. 617-634
https://doi.org/10.1002/adsc.202301161
dc.rights.none.fl_str_mv cc-by (c) Moyano i Baldoire, Albert et al., 2024
http://creativecommons.org/licenses/by/3.0/es/
info:eu-repo/semantics/openAccess
rights_invalid_str_mv cc-by (c) Moyano i Baldoire, Albert et al., 2024
http://creativecommons.org/licenses/by/3.0/es/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 18 p.
application/pdf
dc.publisher.none.fl_str_mv Wiley-VCH
publisher.none.fl_str_mv Wiley-VCH
dc.source.none.fl_str_mv Articles publicats en revistes (Química Inorgànica i Orgànica)
reponame:Recercat. Dipósit de la Recerca de Catalunya
instname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
instname_str Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
reponame_str Recercat. Dipósit de la Recerca de Catalunya
collection Recercat. Dipósit de la Recerca de Catalunya
repository.name.fl_str_mv
repository.mail.fl_str_mv
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